ORGNSunday, April 6, 2008

1:00 PM-5:00 PM Morial Convention Center -- Rm. R06, Oral
Asymmetric Reactions and Syntheses
Presiding:Dong Xiao
1:00 PMYtterbium acetate promoted asymmetric reductive amination: Significantly enhanced stereoselectivity
Thomas C. Nugent, Mohamed M. El-Shazly, Vijay N Wakchaure
1:20 PMAsymmetric bis-boranes as bidentate catalysts
Andrew A. Rodriguez, Kenneth J. Shea
1:40 PMAsymmetric formation of allylic amines with nitrogen-substituted quaternary stereocenters by palladium(II)-catalyzed aza-claisen rearrangements
Daniel F. Fischer, Zhuo-qun Xin, René Peters
2:00 PMCu-catalyzed asymmetric conjugate additions of organoaluminum reagents to cyclic enones: Novel NHC ligands for the formation of all carbon quaternary stereogenic centers
Tricia L. May, M. Kevin Brown, Amir H. Hoveyda
2:20 PMEffect of the backbone geometry on the configuration stability of the asymmetric nitrogen in an N/P ligand during a palladium catalyzed asymmetric allylic substitution
Marc Petit, Guillaume Nonglaton, Verena Schnitzler, Pascal Janvier, Bruno Bujoli
2:40 PMEnantioselective synthesis of planar-chiral ferrocenes by asymmetric ring-closing metathesis
Masamichi Ogasawara, Susumu Watanabe, Kiyohiko Nakajima, Tamotsu Takahashi
3:00 PMHighly enantioselective indium-mediated allylation of ketimine hydrazones
Gregory R. Cook, Robert Kargbo, Ryuji Hayashi, Yoko Takahashi
3:20 PMHydrogenation of vicinal diketones over cinchona alkaloid modified platinum
Igor Busygin, Esa Toukoniitty, Ville Nieminen, Antti Taskinen, Dmitry Yu. Murzin, Reko Leino
3:40 PMPalladium-catalyzed asymmetric synthesis of axially chiral allenylsilanes and their application in chirality transfer reactions
Masamichi Ogasawara, Atsushi Okada, Sebastian Sögel, Tamotsu Takahashi
4:00 PMPendant Co(III)-salen polymer brush catalysts for the kinetic resolution of epichlorohydrin
Christopher S. Gill, Christopher W. Jones
4:20 PMRegioselective insertion of internal, unsymmetrical alkynes in asymmetric rhodium-catalyzed [2+2+2] cycloadditions
Rebecca A Keller, Tomislav Rovis
4:40 PMAsymmetric allylic amines formation via iridium catalyzed carbon-carbon bond forming hydrogenations
Ming-Yu Ngai, Andriy Barchuk, Michael J Krische

Previous Session -- Asymmetric Reactions and Syntheses

Symposium Grid -- Division of Organic Chemistry -- Session Listing

The 235th ACS National Meeting, New Orleans, LA, April 6-10, 2008