Functionalized polyamines with selective binding to TAR RNA

CARB 5

Daniel H. Appella, Laboratory of Bioorganic Chemistry, NIDDK, DHHS, National Institutes of Health, 9000 Rockville Pike, Bethesda, MD 20892
A new class of functionalized polyamines with RNA-binding properties has been developed. These molecules are derived from amino acids, and the synthesis proceeds by reductive amination between alpha-amino aldehydes. The resulting oligomers have been tested for binding to TAR RNA, an RNA fragment with a stem-loop structure that is important for replication of HIV. The results of binding studies will be presented, along with recent results from cell-based assays. Finally, the extension of this chemistry to the synthesis of combinatorial libraries along with high throughput screens for RNA binding will be described.
 

RNA as a Drug Target
8:20 AM-1:20 PM, Sunday, April 6, 2008 Morial Convention Center -- Rm. 214, Oral

Division of Carbohydrate Chemistry

The 235th ACS National Meeting, New Orleans, LA, April 6-10, 2008