ORGN 98 |
| Upon treatment with Martin's sulfurane, secondary alcohols typically undergo dehydration. However, we recently found that under the same conditions, a propargylic alcohol did not afford the expected olefin, but instead underwent an unprecedented oxidation. We present here a study of the steric and electronic effects of secondary alcohols on reaction with Martin's sulfurane.
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Physical Organic Chemistry, Combinatorial and Process Chemistry, New Reactions and Methodology, Peptides, Proteins and Amino Acids
8:00 PM-10:00 PM, Sunday, April 6, 2008 Morial Convention Center -- Hall A, Poster
Division of Organic Chemistry |
