Origins of selectivity in Pd-catalyzed C-N bond-forming reactions using biarylphosphine ligands

ORGN 936

Mark R. Biscoe, mbiscoe@mit.edu, Timothy E. Barder, and Stephen L. Buchwald, sbuchwal@mit.edu. Department of Chemistry, Massachusetts Intstitute of Technology, 77 Massachusetts Ave, Cambridge, MA 02139
The origins of selectivity in Pd-catalyzed C-N cross-coupling reactions using biarylphosphine ligands will be discussed using experimental and computational data.
 

Heterocycles and Aromatics
8:00 AM-12:00 PM, Thursday, August 23, 2007 BCEC -- 254 A/B, Oral

Division of Organic Chemistry

The 234th ACS National Meeting, Boston, MA, August 19-23, 2007