ORGN 122 |
| The focus of this work is on the ortho-quinone methides generated in situ from the reaction of Fischer carbene complexes and propargyl ethers that undergo pericyclic reactions either by electrocyclization to give chromens or Diels-Alder reactions giving hexahydrodibenzopyrans. The scope of these tandem benzannulation / pericyclic reactions will be discussed. Stereochemical induction will be presented and discussed.
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Process R&D, Physical Organic Chemistry, Heterocycles, Aromatics, Metal-Mediated Reactions
8:00 PM-10:00 PM, Sunday, March 25, 2007 Hyatt Regency Chicago -- Riverside Center, Poster
Division of Organic Chemistry |
