ORGN 586 |
| C-N functional group is one of the most important functional groups. Gold(I) and silver(I), bound by different pyridine-based ligands, efficiently catalyze olefin aziridation. Carbene insertion into benzene and intramolecular C-H amidation could also be achieved with our gold and silver system, respectively. More importantly, with modified ligand system, intermolecular C-H amidation of variety of substrates could also be achieved. |
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Metal-Mediated Reactions and Syntheses
1:00 PM-4:20 PM, Wednesday, March 28, 2007 McCormick Place Lakeside -- Room E350, Level 3, Oral
Division of Organic Chemistry |