ORGNWednesday, 13 September 2006

8:00 AM-12:00 PM Moscone Center -- Room 133, Oral
New Reactions and Methodology
Presiding:R. J. Cvetovich
8:00 AMOxidative Mannich reaction catalyzed by dirhodium caprolactamate
Arthur J. Catino, Jason M. Nichols, Brian J. Nettles, Michael P. Doyle
8:20 AMPalladium-catalyzed cross-coupling of heterocyclic silanolates with aryl halides
Scott E. Denmark, John D. Baird
8:40 AMReversing the role of the metal-oxygen pi bond: Re(V)-oxo catalyzed hydrosilylations
Kristine A. Nolin, Jennifer R. Krumper, Joshua J. Kennedy-Smith, Richard W. Ahn, F. Dean Toste
9:00 AMReduction of nitriles with aminoborane under mild reaction conditions
Lubov Pasumansky, Bakthan Singaram
9:20 AMAlkali metals in silica gel as mild and efficient detosylation reagents for secondary amines
Partha Nandi, James E Jackson, Mikhail Y. Redko, James L Dye, Michael Lefenfeld
9:40 AMDevelopment of Fmoc-protected acyl imines for C-C bond-forming reactions: The direct synthesis of Fmoc-protected amines
Timothy J. Peelen, Cheryl L. Brophy, Alison E. Hartman
10:00 AMDiastereoselective allylation and crotylation of N-unsubstituted imines derived from ketones
Avinash N. Thadani, Bhartesh Dhudshia
10:20 AMEfficient Strecker reactions of ketones and fluorinated ketones towards the synthesis of α–aminonitriles and their fluorinated analogs using gallium(III) triflate as a catalyst
G. K. Surya Prakash, Thomas Mathew, Chiradeep Panja, Steevens Alconcel, George A. Olah
10:40 AMSynthesis of L-aspartyl-α-aminocyclobutanecarboxylic acid methyl ester by Ugi reaction
Jianmei Wang, Michael C. Pirrung
11:00 AMNovel metal-free coupling reaction of azoles with 2- or 3-haloindoles
Martin Poirier, Sébastien R. Goudreau, Jason Poulin, Jolaine Savoie, Pierre L. Beaulieu
11:20 AMIntramolecular cycloaddition cascade of 1,3,4-oxadiazoles
James R. Fuchs, Gregory I. Elliott, Brian S. J. Blagg, Hayato Ishikawa, Houchao Tao, ZhongQing Yuan, Dale L. Boger
11:40 AMImidazolidinone chiral auxiliaries for the stereoselective synthesis of azetines and β-amino carbonyl derivatives bearing a quaternary center
Christopher J. MacNevin, Dennis C. Liotta

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The 232nd ACS National Meeting, San Francisco, CA, September 10-14, 2006