ORGNMonday, 11 September 2006

8:00 AM-12:00 PM Moscone Center -- Room 133, Oral
Metal-Mediated Reactions and Syntheses
Presiding:Gregory R. Cook
8:00 AMRate-limiting reductive elimination and variable olefin effects in nickel-catalyzed anhydride alkylation
Jeffrey B Johnson, Tomislav Rovis
8:20 AMMechanistic and stereochemical investigations of palladium-catalyzed intramolecular hydroaminations of unactivated alkenes
Forrest E. Michael, Brian M. Cochran
8:40 AMSynthesis of oxygen heterocycles via Pd-catalyzed olefin carboetherifcation
Michael B. Hay, John P. Wolfe
9:00 AMNovel synthesis of 2-alkenyl and 2-arylbenzimidazoles
Jeremiah W. Hubbard, Björn C. G. Söderberg, Adam M. Piegols
9:20 AMPalladium-catalyzed synthesis and transformation of allylboronic acids
Kalman J. Szabo
9:40 AMDecarboxylative coupling of aromatic carboxylates: A novel synthesis of biaryls
Lukas J. Goossen, Laura M. Levy, Bettina Melzer
10:00 AMMild and phosphine-free Suzuki-Miyaura coupling reaction catalyzed by Pd/C
Yoshiaki Kitamura, Satoko Sako, Takahiro Udzu, Ai Sakurai, Asami Tanaka, Yusuke Kobayashi, Utpal Bora, Takanori Kurita, Atsushi Kozaki, Tomohiro Maegawa, Hironao Sajiki
10:20 AMPd-catalyzed carbonylation of aryl tosylates and sulfonates
Chaoxian Cai, Nelo Rivera, Jaume Balsells-Padros, J. Chris McWilliams, Rick Sidler, Yongkui Sun, David J. Mathre
10:40 AMPalladium-catalyzed cascade annulation of unactivated secondary halides
Alena Rudolph, Nils Rackelmann, Mark Lautens
11:00 AMEnantioselective catalyses using SPRIX ligands and novel spiro isoxazoline-isoxazole hybrid ligands
Priti S. Koranne, Tetsuya Tsujihara, Shinobu Takizawa, Junichi Yogo, Kiyotaka Onitsuka, Hiroaki Sasai
11:20 AMInter- and intramolecular, homo- and cross-coupling radical reactions: Diastereoselectivity introduced by a transition metal cluster
Gagik Melikyan, Aaron Rowe, Arthur Floruti, Christopher Wild, Lucin Devletyan, Nenuphar Nezami, Louis Carlson, Yasuko Hirakawa, Norman Dean
11:40 AMPotassium permanganate/carboxylic acid/organic solvent: A powerful substitute for manganese(III) acetate
Ayhan S. Demir, Hamide Findik

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The 232nd ACS National Meeting, San Francisco, CA, September 10-14, 2006