ORGN 156 |
| Dynamic kinetic resolution (DKR) is evolving as an effective technique for synthesizing enantiomerically-enriched products in high yields from racemic substrates. We have used immobilized lipases and immobilized palladium complexes in DKR of substituted 1-phenylallyl acetates. We have obtained the corresponding allylic alcohols in high yields and high enantioselectivities. |
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Asymmetric Reactions and Syntheses, Metal-Mediated Reactions, Combinatorial, Parallel, and Solid-Phase Chemistry
8:00 PM-10:00 PM, Sunday, 10 September 2006 Moscone Center -- Hall D, Poster
Division of Organic Chemistry |