ORGN 481 |
| We report the first general synthesis for O-alkylarylhydroximoyl azides. This synthesis produces a single geometric isomer. These organoazides offer potential routes to heterocyclic systems containing oxime ether substituents of specific stereochemistry. A series of these compounds with ring substituents varying from electron-donating to electron-withdrawing were produced. The stability of these compounds and their reactivity in Schmidt-type rearrangements and 1,3-dipolar addition reactions will be discussed. |
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New Reactions and Methodology, Heterocycles and Aromatics, Bioorganic Chemistry
8:00 PM-10:00 PM, Tuesday, 12 September 2006 Moscone Center -- Hall D, Poster
Division of Organic Chemistry |