ORGN 919 |
| A catalytic enantioselective total synthesis of naturally occurring anticancer product (-)-pironetin will be described. The synthesis is characterized by extensive use of reaction methodologies based on catalytic asymmetric acyl halide-aldehyde cyclocondensation (AAC) reactions. The synthesis also incorporates an iridium-catalyzed olefin isomerization. |
|
Total Synthesis of Complex Molecules
1:00 PM-5:00 PM, Thursday, 14 September 2006 Moscone Center -- Room 134, Oral
Division of Organic Chemistry |