Controlling the aspect ratio of a well-defined self-assembled bis-ureido based surfactant aggregate

ORGN 284

Matthijn Vos, m.r.j.vos@tue.nl1, Philippe Leclère, philippe.leclere@umh.ac.be2, Roeland JM. Nolte, R.Nolte@science.ru.nl3, and Nico A. J. M. Sommerdijk, N.Sommerdijk@tue.nl1. (1) Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, Den Dolech 2, 5600 MB Eindhoven, Netherlands, (2) Laboratory for Chemistry of Novel Materials, University of Mons-Hainaut, Place du Parc, 20, B - 7000 Mons, Belgium, (3) Institute for Molecules and Materials, Radboud University, Toernooiveld 1, 6525 ED Nijmegen, Netherlands

Self-assembled surfactant aggregates show a large variety in shapes and sizes. Although in some cases the shape can be predicted using the postulates of Israelachvili, what exactly governs the size of the aggregates is not fully understood. It is obvious that the size of well defined self-assembled objects is determined by a fine balance between attractive and repulsive forces. Understanding these forces may lead to control over the dimensions of the aggregates. We present a surfactant molecule (1), in which a bis-ureido group is incorporated in its hydrocarbon chain. Due to strong hydrogen bonds in the length direction, 1 forms well-defined highly ordered ribbon-like aggregates in water. The aspect ratios of these ribbons can be varied between 2.5 to >50 in a controlled manner, using only temperature and concentration. The H-bonds are mainly influenced by temperature and control the length, whereas the width can be controlled by changing concentration.