ORGN 367 |
| The recent developments of metal-catalyzed silylene transfer reactions to imines are presented. Synthetically useful silaaziridines are obtained from the transfer reactions. The scope and limitations of silaaziridine formation are introduced. A systematic study of the reactivity of silaaziridines is also presented which revealed a variety of insertion reactions depending on the reaction conditions employed and the substitution pattern of the silaaziridines. Among these, unexpected dearomatization-cyclization reactions and palladium catalyzed alkyne insertion reactions are shown as well as the development of synthetically useful transformations.
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New Reactions and Methodology
8:00 AM-12:00 PM, Tuesday, 12 September 2006 Moscone Center -- Room 133, Oral
Division of Organic Chemistry |
