ORGN 890 |
| The conjugate additions of different carbon nucleophiles to cyclopentadienone substrates (1 and 2) with one free hydroxyl functional group were investigated to determine the role of the hydroxyl group in determining regiochemistry. During this reaction an unexpected intramolecular displacement of OTBS by the enolate intermediate occurs, to afford cyclopropane derivatives.
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New Reactions and Methodology
8:00 AM-11:40 AM, Thursday, 14 September 2006 Moscone Center -- Room 133, Oral
Division of Organic Chemistry |
