ORGNSunday, 26 March 2006

8:00 PM-10:00 PM Georgia World Congress Center -- Ex. Hall B4, Poster
Asymmetric Reactions and Syntheses, Physical Organic Chemistry, Combinatorial Chemistry, Total Synthesis
Organizer:Robert D. Larsen
Using the microenvironment of polymers to affect reactivity of polymeric reagents
James R. Blanton
Combining chiral elements in Asymmetric Phase-Transfer Catalysts: Styrene oxide and chiral α, α'-disubstituted pyrroline and piperidine derived structures
Gregory Grover, Walter E. Kowtoniuk, Darren K. MacFarland
Development of organocatalysts for Michael addition of aldehydes to enones
Yonggui Chi, Timothy J. Peelen, Samuel H. Gellman
Binaphthyl-based bifunctional organocatalyst-promoted enantioselective Morita-Baylis-Hillman reactions
Jian Wang, Hao Li, Liansuo Zu, Wei Wang
Binaphthyl-based bifunctional organocatalyst-promoted enantioselective Michael addition of 1,3-diketones to nitroolefins
Jian Wang, Hao Li, Liansuo Zu, Wei Wang
Chiral pyrrolidine sulfonamide-promoted direct, highly enantio- and diastereoselective Michael addition of ketones to enones
Jian Wang, Hao Li, Liansuo Zu, Wei Wang
Synthesis of unsymmetrical chiral salens
Caroline Burd, Michael Holbach, Xiaolai Zheng, Christopher W. Jones, Marcus Weck
Designing catalysts for the asymmetric epoxidation of alkenes
Emer Ward, Matthias Voegler, Eoin F Clarke, Declan Gilheany
An L-phenylalanine-derived oxadiazinone: Its synthesis and efficacy as a chiral auxiliary in asymmetric aldol additions
Delvis D. Dore, Shawn R. Hitchcock
The development of a chiral auxiliary and its application towards the total synthesis of tolterodine(Detrol LA)
Ryan A. Davis, Shawn R. Hitchcock
Towards the total synthesis of (R)-arundic acid utilizing oxadiazinones as chiral auxiliaries
Lisa J. Sinnott, Shawn R. Hitchcock
Oxadiazinones as chiral auxiliaries: The asymmetric synthesis of a proposed hydroxyethyl isostere of a Human T-cell Leukemia virus (HTLV-1) protease inhibitor
Raleigh W. Parrott II, Shawn R. Hitchcock
The triazinones: Towards the synthesis of a new class of chiral auxiliaries
Jonathan A Groeper, Shawn R. Hitchcock
Progress toward improving the diastereoselectivity of the Meyers ortho-alkylation of chiral aromatic oxazolines
Julianne McLaughlin, Jason S. Overby, Justin K. Wyatt
Developing a pseudoephedrine chiral resin for asymmetric, solid phase library synthesis
David J. Procter, Andrea M. McGhee, Glynn Williams, Jean-Claude Kizirian
Synthesis, purification, and characterization of ethylene glycol ether aldehydes
Aaron D. Gross, Lakshmaiah Sreerama, Daniel Gregory
Kinetic and dynamic kinetic resolution of allylic acetates using immobilized lipases
Ekaterina N. Kadnikova, Vikalp A. Thakor
Asymmetric reduction of alpha-ketoesters catalyzed by a 7-hydroxysteroid dehydyrogenase from Bacteroides fragilis
Dunming Zhu, Jenny Sterns, Monica Ramirez, Ling Hua
Optimization of a catalytic enantioselective allylic substitution reaction that gives access to chiral alpha-substituted allylic boronates and their addition to aldehydes
Lisa Carosi, Dennis G. Hall
Application of N-acyliminium ions in the asymmetric synthesis of indole alkaloids
Christopher I Thomas, Steven M Allin
[2,3]-Sigmatropic rearrangements of ammonium ylides
Robert E. Gawley, Kwangyul Moon, Daniel Eddings
Multi-step syntheses of the intermediates of Spirastrellolide A
liza Shrestha, Ce Wang, Craig J. Forsyth
Desymmetrization efforts towards fostriecin
James P. McParland, Stephen R. Sieck, Alan Whitehead, Paul R Hanson
Functionally-active phosphate tethers: Progress towards the synthesis of dolabelides
Joshua D. Waetzig, Alan Whitehead, Paul R Hanson
From catechol to sugar: A new synthetic application of asymmetric catalysis
Alina Ariosa Alvarez Jr., Padraic McGovern, Lorna Kennedy
Non-mevalonate pathway: Synthesis of MEP pathway intermediates and their derivatives
Chandraiah Lagisetti, Robert M. Coates
Air-stable chiral primary phosphines
Rachel M Hiney, Lee J Higham, Declan G Gilheany
Organic alicyclic crystals form in seconds, designing an amide for facile crystallization
T. Gordon Scott, Abdul K. Mohammed
Coupling reaction of alkylcarbonyloxymethyl halides with phenols: Reevaluating the influence of steric hindrance
Joshua D. Thomas, Kenneth B. Sloan
Mechanism of hydrolysis of N-alkyl-N-alkyloxycarbonyl-aminomethyl and N-aryl-N-alkyloxycarbonylaminomethyl derivatives of phenols and carboxylic acids
Susruta Majumdar, Kenneth B. Sloan
Dianion of tetrabenzo[5.7]fulvalene: The study of the aromaticity/antiaromaticity continuum via dianions
Ashley Mynar, Nancy S. Mills, Abraham Yousef
Long distance radical cation migration in DNA condensates
Prolay Das, Gary B. Schuster
Role of N1 imino proton in long distance charge transfer through DNA
Avik Ghosh, Gary B Schuster
Distance independent charge transport across low-energy barriers in DNA
Joshy Joseph, Gary B Schuster
Pdn and Run (n=1-6) cluster interaction with small organic molecules: A DFT study
Jesse J. Lutz, Dalila G. Kovacs
Bromo-nitro-sulfolene Halogen Dance
Jeffrey E. Elbert, Valentina M. Berestovitskaya, Irina E. Efremova, Victoria V. Abzianidze
Reduction of nitroarenes by hydroxide ion in water catalyzed by beta-cyclodextrin: Enhanced reactivity of hydroxide ion
Yun Lu, Gary Diffee, Bo Liu
Electron acceptor-induced isomerization of aryl [6,5] open fulleroids to [6,6] closed methanofullerenes and the electrochemical evaluation of their free energy difference
Melvin H. Hall, Philip Shevlin, Huajun Lu, Anthony Gichuhi, Curtis Shannon
Synthesis and identification of the isomers of beta-chlorocinnamohydroximoyl chloride
James E. Johnson, Ling Lu, Hauquan Dai
pH-Rate studies and buffer catalysis of the aqueous reaction of α-hydroxyhippuric acid derivatives
Richard W. Nagorski, Lesley N. Skelton
Kinetic and mechanistic aspects of oxidation of N-Phenyl acetamides by N-bromophthalimide in presence of excess of mercuric acetate
Pabba Srinivas, Amena Anjum
Vinylcarbene and propenylidene in C3H4 rearrangements at 10 K
Susan Przybylinski Lucas, Robert J. McMahon
Addition of dihalocarbenes to benzyl[1.1.1]propellane
Dina C. Merrer, Chantel I. Nicolas
Aromaticity and antiaromaticity of dianions and dications of benzylidenefluorenes
Nancy S. Mills, D Vasudevan
Spin alignment in ferrocenylsilanes
Silvia Atim, Trent D. Selby
Pericyclic chemistry of spiro[2.4]hept-2-yne
Guilan Pan, John C. Gilbert
Computational and experimental evidence for the SE2 mechanism
Stephen C. Waller
Experimental and theoretical NMR studies on the cleavage of highly substituted diastereomeric epoxides with organoalane reagents
Gerardo Torres, Wildeliz Torres, Jonas M Vilkas, Yasuyuki Ishikawa, José A. Prieto
Thermodynamics and kinetics of monohalogenation of 2,2,5,5-tetramethylimidazolidin-4-one: A theoretical study
Akin Akdag, Michael L. McKee, S. D. Worley
Titanosilicate molecular sieve as a photocatalyst for size-screening conversion
Yasuhiro Shiraishi, Naoya Saito, Takayuki Hirai
Adsorption-controlled selective photocatalytic transformation on mesoporous titanium dioxide
Yasuhiro Shiraishi, Naoya Saito, Takayuki Hirai
Release of ketones and aldehydes from alkyl enol ethers via photoinduced electron-transfer
Promise K. Yong, Judy Miska, Jessica Herron, Anamitro Banerjee
Synthesis and investigation of photoactivated artificial metalloproteases
Eric S. Oshige, Paul B. Jones
Design of a new photoremovable protecting (caging) group
Anton Kulikov, Vladimir Popik
Parallel synthesis of aminomethylcyclopropanes using catch and release purification: Synthesis of serotonin reuptake inhibitors
Timothy M. Gregg, Huw M. L. Davies, Peter Scott
Synthesis and evaluation of amphiphilic quaternary ammonium antimicrobials
James H. Wynne, William L. Straube, Arthur W. Snow, Joanne M. Jones-Meehan
Efficient selective reduction: The parallel synthesis of 1,2,3,4-tetrahydro-ß-carboline derivatives
Guobin Miao, Audra Dalton, Revell Sandberg-Diment, Ruoxi Lan, Chi Le, C-S. Lee, Libing Yu
Comb-like poly-N-substituted glycines as monodisperse drag-tags for free-solution DNA sequencing by capillary electrophoresis
Russell D Haynes, Robert J Meagher, Jennifer Coyne, Annelise E. Barron
High load soluble oligomeric triphenylphosphine: Applications in organic synthesis
Thiwanka Samarakoon, Andrew M. Harned, Paul R. Hanson, Daniel L. Flynn
Application of polymer-bound palladacycles as reagents for the synthesis of combinatorial libraries of 2H-1-benzopyrans and 1,2-dihydroquinolines
John C. Hershberger, Lei Zhang, Genliang Lu, Helena C. Malinakova
Silica supported sulfonic acids: Versatile and useful products for purification
Geneviève Gingras, Delphine Desplantier-Giscard, Michel Morin, Jean-Louis Cabral, François Béland
High–load ROMP-derived oligomers with tunable properties: Applications in library generation
Punitha Vedantham, Jennifer Guerra, Parul J Gor, Mianji Zhang, Maria del Sol Jiménez, Gunda I. Georg, Paul R Hanson
Amino acids as building blocks for dynamic combinatorial libraries
Sophie Klein, Eric J. Enholm
Efficient synthesis of β-peptide combinatorial libraries with microwave irradiation
Justin K. Murray, Jack D. Sadowsky, Samuel H. Gellman
Olefin metathesis of peptide derivatives in dynamic combinatorial chemistry
Tammy K. C. Low, Eric Enholm
Anthranilic acid derivatives via vicarious nucleophilic substitution
Takashi Naka, Hiroshi Iwamura, Takashi Yamazaki, Tadashi Shirasaka
14-Hydroxylation of opiates: Catalytic direct autoxidation of codeinone to 14-hydroxycodeinone
Qibo Zhang, Joseph O. Rich, Peter C. Michels, Ian C. Cotterill, David P. Pantaleone
Direct and scalable method for the synthesis of (2R,3S)-3-N-tert-butoxycarbonylamino-1,2-epoxy-4-phenylbutane
Yasuyuki Otake, Tomoyuki Onishi, Naoko Hirose, Kunisuke Izawa
Efficient synthesis of AG7172 via a diastereoselective 1,4-addition
Chunrong Ma, Qingping Tian, Jill Scott, Naresh Nayyar, Mark Guzman
Synthesis of the CXCR3 antagonist AMG 487
Michael G. Johnson, An-Rong Li, Jiwen Liu, Andrew P. Marcus, Alan X. Huang, Julio C. Medina
Regio- and stereoselective synthesis of (1R,2S,4R)-5,5-difluorobicyclo[2.2.1]-heptan-2-amine
Aiwen Li, Christopher H. Fotsch, David J. St. Jean Jr., Chester Yuan
Microwave-assisted synthesis of neopentylethynlarylboronates for the construction of boronic acid-based fluorescent sensors for carbohydrates
Shi-Long Zheng, Suazette Reid, Regan LeBlanc, Binghe Wang
Effect of conjugation with a phenylethynyl group on the fluorescent properties of water-soluble arylboronic acids
Shi-Long Zheng, Na Lin, Suazette Reid, Binghe Wang
Synthesis and spectral characterization of 10-hydroxycamptothecin
Chun-Yan Xu, Ming-Zhi Huang
Copper-catalyzed synthesis of new water-soluble 10-hydroxycamptothecin analogues
Chun-Yan Xu, Ming-Zhi Huang
Alkylation of cyclen, a key step in the asymmetric synthesis of (R)-DOTAGA(t-Bu)4
Kevin L. Zhou, Vincent Jacques, Shirley Kalogeropoulos, Stuart G. Levy, John C. Amedio
Synthesis of novel Sansalvamide A derivatives
Thomas J. Styers, Rodrigo A. Rodriguez, Ahmet Kekec, Julia Cajica, Joe D. Brown, Shelli R McAlpine
Potent antitumor agents: Sansalvamide A derivatives
Rodrigo A. Rodriguez, Katerina Otrubova, Thomas J. Styers, Po-Shen Pan, Julia Cajica, Emily Parry, Ahmet Kekec, Kathleen McGuire, Shelli McAlpine
Studies toward the total synthesis of ageliferin
Robert W. Huigens III, Christian Melander
Face-selective Diels-Alder reaction of (1R,5R)-3-cyano-6,6-dimethylbicyclo[3.1.1]hept-3-en-2-one: Total synthesis of xenitorins B and C
Hsing-Jang Liu, Wen-Sheng Chang, Kak-Shan Shia
First and catalytic enantioselective total synthesis of 5-demethoxyfumagillol
Chengyong Li, Dan Yang
Paper Withdrawn
Efforts toward the divergent asymmetric total syntheses of Xenia diterpenoids
Timothy S. Snowden, Murali K. Urlam, Jeremy Carr
Studies towards the synthesis of the C1-C15 fragment of Spirastrellolide A
Juliana L. Asgian, A. R. Chamberlin
Studies toward the total synthesis and absolute configurational determination of (+)-varitriol
Ryan T. Clemens, Michael P. Jennings
Synthesis of arylnaphthalene lignans
Shingiria Chirisa, William A. Feld
Studies toward the synthesis of vineomycinone B2 methyl ester
Chi-Li Chen, Stephen F. Martin
Chemo-enzymatic approach towards the capsaicin glucoside
Israt Sultana, Miwa Shimamoto, Rika Obata, Shigeru Nishiyama, Takeshi Sugai
Studies directed towards the total synthesis of (+)-amphidinolide T1
Chandrasekhar Abbineni, Pradip K. Sasmal, K Mukkanti, Javed Iqbal
Studies towards synthesis of C1-C10 fragment of Norbonolide
Prasad.C Narasimhulu, Mohammed Takhi, K. Mukkanti, Javed Iqbal
Studies towards the total synthesis of Tedanolide: Synthesis of C (1) - C (9) fragment
Vijay Kumar Nyavanandi, Srinivas Nanduri, Naidu Andra, Javed Iqbal
Studies towards the total synthesis of (-) Borrelidin: Strategies for the C11-C15 fragment construction and the utility of RCM reaction for macrolide cyclization using model systems
Vamsee K. Chintakunta, Santanu Maitra, K. Mukkanti, Javed Iqbal
Total synthesis of montanin A
Hsing-Jang Liu, Jia-Liang Zhu, I-Chia Chen, Yen-Ku Wu
Synthetic approaches to Plakorthethers and the core of Pseudomonic acid
Alexei V Novikov, Jinu P John, Anna Zhachkina
Enantioselective synthesis of Goniothalamin Oxide
George A. O'Doherty, Philip Ryan Harsh
Studies towards the synthesis of ABCD Rings of azaspiracid
Xiaohua Li, David R. Mootoo
Synthetic and mechanistic studies of diazobenzofluorene natural products and analogs
T. Eric Ballard, Christian Melander
Synthesis of and interstrand DNA cross-linking by aziridinomitosenes
Don L. Warner, Stacia M. Rink, Amber M. Hibberd, Byron D. Knowles, Christopher J. Liby, Andrea Radabaugh, Jennifer R. Spencer, Amy C. Ulappa
Total synthesis of antileishmanial and antibacterial alkaloids (+)-Na-methylpericyclivine and (-)-Na-methylakuammidine as well as the ring A-oxygenated natural products, (+)-10-methoxy Na-methylpericyclivine and 10-hydroxy Na-methylpericyclivine
P. V. V. Srirama Sarma, James M. Cook
General approach for the synthesis of 12-methoxy substitured sarpagine indole alkaloids including 12-methoxy-Nb-methylvoachalotine and fuchsiaefoline
Hao Zhou, James M. Cook
Progress towards the total synthesis of the opioid analgesic indole alkaloids mitragynine and 7-hydroxymitragynine as well as the antimalarial bisindole 10-hydroxysambarensine
Jun Ma, Wenyuan Yin, James M. Cook
Studies toward the synthesis of α-yohimbine by triple annulation
Raghu Ram Chamala, Vijaya N. Desai, Jos P. Varghese, Robert B. Grossman
Variation of steric and electronic parameters of DHIP catalysts
Ximin Li, Hui Jiang, Eric W. Uffman, Vladimir B. Birman

Symposium Grid -- Division of Organic Chemistry -- Session Listing

The 231st ACS National Meeting, Atlanta, GA, March 26-30, 2006