ORGNTuesday, 28 March 2006

8:00 PM-10:00 PM Georgia World Congress Center -- Ex. Hall B4, Poster
New Reactions and Methodology, Bioorganic Chemistry, Molecular Recognition and Self Assembly
Organizer:Robert D. Larsen
Solution and solid phase synthetic approaches to Laulimalide analogs
Eric A. Tanifum, Ian McAlexander, Bradley S Davidson
Guanidines as asymmetric organocatalysts
Sheryl L. Wiskur
Phosphorus-carbon bond-formation by cross-coupling of hypophosphorous acid derivatives with allylic electrophiles
Karla Bravo-Altamirano, Jean-Luc Montchamp
Study of the alkylation of H-phosphinate esters under basic conditions
Isabelle Abrunhosa-Thomas, Claire Sellers, Jean-Luc Montchamp
One-pot synthesis of symmetrical bisarylethynes using bis(trimethylsilyl)acetylene and a modification of the Sonogashira coupling reaction
Allen F. Brooks, Batoul S Dagher, Jeffrey P. Guina, Anne E. Labut, Matthew J. Mio, Nicholas D. Ball, Elodie E. Marlier, Ronald G. Brisbois
Ethynylsilane deprotection utilizing 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), copper (I) iodide and water
Allen F. Brooks, Batoul S Dagher, Isaac Z. Davidovich, Jeffrey P. Guina, Jessica A. Heidt, Amie D. Hinshaw, Anne E. Labut, Ally M. Pember, Bryan P. Vos, Matthew J. Mio
Developing further the Suzuki cross-coupling reaction of potassium vinyltrifluoroborate with highly hindered aryl bromides for use as a key intermediate for future Cytosporone E derivatives
Rhiannon R. Carter, Justin K. Wyatt
Palladium-catalyzed alpha-arylation of zinc enolates of esters and amides
Takuo Hama, John F. Hartwig
α-Arylation of cyclopentanone: Palladium-catalyzed coupling of enamines and aryliodides
James C. Adrian Jr., Kristina M. Gehring, Eric F. D’Silva, Sarah R. Shea, Tian Tian
New cyanation reaction of boronic acids
Zhihui Zhang, Lanny S. Liebeskind
Room temperature synthesis of highly enantio-pure α-amino ketone and peptidyl ketone by thiol ester and boronic acid cross coupling
Hao Yang, Lanny S. Liebeskind
Preparation and application of novel bismuth reagents for parallel synthesis
Yan Xu
Bismuth nitrate-catalyzed optical resolution of hydroxy β-lactams: Preparation of both enantiomers of the taxol side chain
Bimal K. Banik
Bismuth nitrate-catalyzed synthesis of 3-pyrrole substituted monocyclic β-lactams
Bimal K. Banik
Bismuth nitrate-catalyzed stereospecific glycosylation: Enantiomerically pure β-lactams with thienamycin side chain
Bimal K. Banik
Baylis-Hillman chemistry: Diastereoselective synthesis of both cis and trans alpha-methylene-gamma-lactones
George W. Kabalka, Chunlan Chen, Bollu Venkataiah
Trialkylstannane-mediated cyclizations of α,β-unsaturated carbonyl compounds
John Cran, Marie E. Krafft, Ryan Davoile, Moonki Seok
Rearrangement/cyclization reactions of vinylboronic esters
M. Mark Midland, Diane Hinkens
Tandem reactions using samarium(II) iodide: Sequential conjugate addition/nucleophilic acyl substitution
David J. St. Jean Jr., Edward P. Cheng, Eric A. Bercot
Formation of functionalized cycloalkenes via intramolecular Morita–Baylis–Hillman alkylation using unsaturated thiol esters
Kimberly A. Seibert, Thomas F. N. Haxell, Marie E. Krafft
Organocatalyzed intramolecular Morita-Baylis-Hillman alkylation
Kimberly A. Seibert, Marie E. Krafft
Intramolecular hydrodimerization reaction of alkoxy tether substituted substrates: Retention vs. elimination
Manchanayakage Renuka, Scott T Handy
Theoretical and synthetic studies of 1,5-dipolar electrocyclizations for the synthesis of 2-pyrrolines
Amber M. Hibberd, Derrek N. Woodbury, Jess L. Burleson, Don L. Warner
Synthesis and cycloaddition reactions of ynamides: General methods for the preparation of 3–aminocyclobutenones and polycyclic nitrogen heterocycles
Amanda L. Kohnen, Joshua R. Dunetz, Xiao Yin Mak, Tin Yiu Lam, Rick L. Danheiser
Novel synthesis of pyrroloquinolizidines via a 1,3-dipolar cycloaddition reaction
Xuelei Qian, Steven R. Angle
Paper Withdrawn
Synthesis and structural evaluation of versatile oligoisoxazolidines for proteomimetics
Amelia A. Fuller, Sara J. Buhrlage, Anna K. Mapp
Formation of cyclic ethers via an oxonium ylide mediated [2,3] sigmatropic rearrangement
Lindsay A. Batory, Erik Rogers, Jon T. Njardarson
Microwave assisted single-step synthesis of skeletally diverse compounds from a multicomponent coupling reaction
Soumava Santra, Peter R Andreana
Microwave-assisted one-step synthesis of benzimidazoles
Shou-Yuan Lin, Yuko Isome, Daniel Yohannes, Libing Yu, Jifeng Liu
Defining the utility of the 2,2-dimethyl-4H-1,3-benzodioxin-4-one protecting group as a synthetic handle
Naval Bajwa, Michael P. Jennings
Synthesis of benzodiazepine sulfonamides and their rearrangement to diaryl sulfones
Lisa Marie Neuls, James R McKee, Murray Zanger
Comprehensive approach to the synthesis of sulfate esters
Levi S. Simpson, Theodore S. Widlanski
Supported nucleophiles for rapid removal of Bsmoc-amino protecting group utilizing microwave heating
Shahnaz Ghassemi
New nitrosation method with tin(IV) chloride
Cyril Parkanyi, Benoit Celaries
A general synthesis of quinone ammonium salts: Bifunctional materials for charge-transfer studies
David Wiedenfeld, David R. Glass, Mark Minton, Vladimir Nesterov
Chemistry of [13C]methyl phenyl sulfide
David R. Glass, Rodolfo A. Martinez, David Wiedenfeld, Erick G. Ortiz, Frank E. Anderson III
Synthesis of internal alkynes using alkynylboron dihalides
George W. Kabalka, Min-Liang Yao, Scott Borella
Regioselectivity in a highly efficient, microwave-assisted aminolysis of epoxides
Brendan R. D'Souza, Nick Scowley, Harriet A. Lindsay
An approach to dihydropyran synthesis by vinyl epoxide ring expansion
Kevin J. Quinn, Neal A. Biddick, Brian A. DeChristopher
Applications of a highly enantioselective sulfur-ylide in epoxidation reactions
Catherine P Tubb, Jonathan M Goodman
Development of sulfur ylide technologies
David C. Forbes
Epoxide-based synthetic approach to the C13-C25 fragment of bafilomycin A1
Marlenne Mulero, David Rodríguez, Wilnelia Dávila, José A. Prieto
Lanthanide triflate-catalyzed transacylation of esters and amides using carboxylic acids
Matthew R Hudson, Martin A. Walker
Synthesis of lavandulol and cembrene A via suitable ring-opening protocol starting from carvone
Hee Jin Kim, Sangho Koo
A safe and affordable method for preparing homologated carboxylic acids from aldehydes
Timothy S. Snowden, Lauren R. Cafiero, Giora Lichtenstein
Nicholas cations in the Morita-Baylis-Hillman reaction
Mark Campbell, Marie E. Krafft, Sean Kerrigan
New synthetic method of conjugated allylic sulfones
Se-Young Jung, Jae-Hong Min, Sangho Koo
Proazaphosphatranes: Efficient non-ionic nucleophilic base for the synthesis of β-hydroxy nitriles and β-hydroxy esters
Jesudoss V. Kingston, John G. Verkade
Synthesis of novel aminosilanes for the catalysis of nitroaldol condensations
William D. Buchanan, Jetty L. Duffy-Matzner
Imidazolium-based polymer supported gadolinium triflate as a novel Lewis acid catalyst for Michael additions
Ramesh Alleti, Woon Su Oh, Meher Perambuduru, C. V. Ramana, U. Becker, V. Prakash Reddy
Preparation of polysubstituted aromatic compounds through regioselective disubstitution of arynes
Timothy S. Snowden, Ashok Ganta
BF3-H2O catalyzed hydroxyalkylation of aromatics with aromatic dicarboxaldehydes towards the synthesis of anthracene derivatives
G. K. Surya Prakash, Chiradeep Panja, Anton Shakhmin, Eric Shah, Thomas Mathew, George A. Olah
Oxidation of Isoxazolines: A convenient synthesis of β-dicarbonyl compounds
Daniel P Canterbury, Alison J. Frontier
New reagents for the metal-free one-pot α-functionalisation of carbonyl compounds
Teyrnon C Jones, Niall M Killeen, Kerri L Jones, Nicholas C O Tomkinson, Adrian Hall
Facile preparation of polymer supported N-(2-iodyl-phenyl)-acylamides and their oxidative properties
Uladzimir Ladziata, Jeff Willging, Viktor V. Zhdankin
Oxidation of thiols with poly-styrenehydantoin (PSH) monochloro and dichloro beads
Akin Akdag, Thomas R. Webb, S. D. Worley
An advantageous tetrameric titanium alkoxide/ionic liquid as a recyclable catalyst system for the selective oxidation of sulfides to sulfones
Chinta Reddy Venkat Reddy, John G. Verkade
Synthesis and conformational study of Δ-Phe-derived peptides: Evaluation of role of Δ-Phe in secondary structure generation and cyclization
T. V. R. Sesha Sastry, B. M Rajesh, Jagattaran Das, K Narasimulu, Ajit Chand Kunwar, Javed Iqbal
Design and synthesis of a head-to-head polyamide hairpin dimer targeted to the heat shock response element
Jianfeng Cai, Clayton Hunt, John Stephen Taylor
In vivo directed evolution of a minimalist DNA-binding protein in a modified yeast one-hybrid system
Jing Xu, Hiu Kwan Chow, Jumi A. Shin
Investigations into the mechanism of copper binding by the prion protein
J. Bryant Pollock, Colin S. Burns
Determining the zinc binding region of prothymosin-alpha using peptide models
Chris L. Wilson, Colin S. Burns
Exploring protein-protein interactions in the copper binding region of the prion protein
Angela G. Kenward, Colin S. Burns
Use of the yeast two-hybrid assay to identify bZIP protein interactions with calmodulin
Gang Chen, Jumi A. Shin
Synthesis of novel boronated cyclopentaneamino acids for potential use in neutron capture therapy
George W. Kabalka, Abhijit Navarane, Min-Liang Yao
Syntheses of isotope-labeled and -unlabeled N-beta-naphthyliodoacetamide and application to quantitative analysis of peptides and proteins by stable isotope differential mass spectrometry
Satomi Niwayama, Sadamu Kurono, Hanjoung Cho, Hiroyuki Matsumoto
Synthesis of deuterium and triutium ring labeled dopamine
Marianna Kanska, Malgorzata Pajak, Ryszard Kanski
Enzymatic synthesis of isotopomers of tyramine labeled with deuterium and tritium
Marianna Kanska, Edyta Panufnik, Ryszard Kanski
Tritium and deuterium isotope effects on enzymatic decomposition of L-tryptophan and 5'-hydroksy-L-tryptophan
Marianna Kanska, Elzbieta Boroda, Ryszard Kanski
Design and synthesis of coenzymes for RNA-phosphoesterase deoxyribozymes
Dorn L. Carranza, Robert R. Kane
Chemical mechanism of Sir2 NAD-dependent protein deacetylases
Brian C. Smith, John M. Denu
Synthesis of bicyclic amidines as transition state analogs for glycosyltransferases
Fedra M. Leonik, Nicole A. Horenstein
Inhibition of trypanothione reductase
Anna M. Larson, April K. Wilhelm, David G. Alberg
Synthetic efforts towards non-hydrolyzable analogs of O-acetyl-ADP-ribose
Lindsay R. Comstock, John M. Denu
Mechanism of activation of subtilisn Carlsberg in organic solvents by co-lyophilization with methyl α-cyclodextrin
Ezio Fasoli, Betzaida Castillo, Eduardo Rosario, Vibha Bansal, Amaris Ferrer, Gabriel L. Barletta
Towards homogeneous catalysis in organic solvents: Peg-modified subtilisin Carlsberg as a case study
Yamaris Pacheco, Kai Griebenow, Gabriel L. Barletta
Effect of structural flexibility on the catalytic properties of subtilisin Carlsberg in organic solvents
Vibha Bansal, Elsa Silva, Amaris A. Ferrer, Gabriel L. Barletta
Targeting RNA with cyclic peptide libraries
Virginia A. Burns, Christian Melander
Use of one-bead, one-compound acetyl-peptide libraries and quantum dots to probe deacetylase specificity
Adam L. Garske, John M. Denu
Cleavage of poly-His tags: Applying protein-protein interactions to promote proper structure
I-San Chan, Anna V. Fedorova, Jumi A. Shin
Enzymatic synthesis of phosphoroselenoate hammerhead ribozyme and their activity study
Gary E. Brandt, Zhen Huang
Synthesis of pyrrole modified DNA for DNA-assisted superstructure formation
Gozde Guler, Gary B. Schuster
DNA-assisted aniline superstructure formation
Bhaskar Datta, Gary B. Schuster
Synthesis of a novel 2'-Se-uridine phosphoramidite and its incorporation into oligonucleotides for X-ray crystal structure determination
Jozef Salon, Guexiong Chen, Yoani Portilla, Markus W. Germann, Zhen Huang
Synthesis of exo-4-selenothymidine triphosphate and its incorporation into oligonucleotides for structural study
Julianne Caton-Williams, Zhen Huang
Synthesis and properties of RNA containing imidazole modified G-U wobble base pairs
Eriks Rozners, Chika Uchiyama, Romualdas Smicius
Monitoring of microenvironmental changes in the major and minor grooves of DNA by dan-modified oligonucleotides
Kimura Takumi, Kawai Kiyohiko, Majima Tetsuro
The protection and deprotection of selenide functionality for Se-nucleic acid synthesis
Charity Igunbor, Nina Logan, Hays Davis, Arlyne B. Simon, Zhen Huang
A novel methodology for the synthesis of fumerates and maleates
Wayne S Price, Ayesha Ahmad, Michael R. Jorgensen, Andrew D. Miller
Targetting PPARs for the treatment of the metabolic syndrome, diabetes type II and neurological diseases
Anju H Yushma Bhurruth, Michael R. Jorgensen, Andrew D. Miller
Formation of fatty ester diols by autoxidation: Mechanistic studies towards the development of a radical clock
Christopher L. Rector, Alan R. Brash, Donald F. Stec, Ned A. Porter
Synthesis of uprolides I-L: 3,7-Oxa-bridged cembranolide analogs from eupalmerin acetate
Brunilda Vera, Abimael D. Rodriguez
Cluster of novel terpenoids from the Caribbean soft coral Pseudopterogorgia elisabethae (Bayer)
Ileana I. Rodríguez, Abimael D. Rodríguez
New diterpenes of the pseudopterane class from two closely related Pseudopterogorgia species: Isolation, structural elucidation, and biological evaluation
Jeffrey Marrero, Claudia A. Ospina, Abimael D. Rodrígiuez, Raphael G. Raptis, Peter Baran, Scott G. Franzblau, Eduardo Ortega-Barria
Semisynthesis of Coβ-cyanobenzimidazolylcobamide
Tilak Chandra, Shawn Zou, Kenneth L Brown
Novel solid-state fluorescent chemosensors based on the photoexcitation energy migration: General design and applications
Huating Zhang, Evgueni E. Nesterov
Rational design and synthesis of fluorescent biosensors based on PET
Ruisong Xu, Irene Kiragu, Charles Cook, Matthew McCarroll, Lichang Wang, Daniel J. Dyer
Synthesis and development of Peptide-based Borono-Lectins (PBLs) for selective saccharide sensing
Yuejiao Zou, John J. Lavigne, Dana L Broughton, Paul R. Thompson
Promotion of extended peptide conformation through hydrogen bonding
Brian R. Linton, Timothy J. Cashman, Henry R. Brennan, Scott A. Barbuto, Ryan A. Brawn
Synthesis and biological evaluation of hydrogen-bond surrogate based artificial alpha-helices
Deyun Wang, Gianluca Dimartino, Paramjit S. Arora
Nonpeptidic foldamers from amino acids: Synthesis and characterization of 1,3-substituted triazole oligomers
Nicholas G. Angelo, Paramjit S. Arora
A synthetic pi-helix: Application of the hydrogen bond surrogate strategy to diverse folded structures
Ross Chapman, John L. Kulp III, Paramjit S. Arora
An iterative templated synthesis strategy for the evolution of DNA-binding small molecules
Christine L. Heinecke, Christian Melander
De novo structure-based design of bis-urea hosts for tetrahedral oxoanion guests
Benjamin P. Hay, Vyacheslav Bryantsev
Novel amphiphilic self-assembling bis-urea macrocycles
Jun Yang, Linda S. Shimizu
Binding properties of self-assembling bis-urea macrocyclic tubular structures
Mahender B. Dewal, Linda S. Shimizu
Solid-state host to study arene-anion complexes
Michael Lewis, Aimee Clements, Isaree Darachai
Self-assembly of novel pyrogalloarenes
Eric Dueno, Cesar Zambrano, Jorden Kass, Leslie Slasor, Jennifer Skaggs
Self-assembled G-quadruplexes based on 8HetdG analogs
Vladimir Gubala, Gerard Hobley, José M. Rivera
Characterization of functionalized single walled nanotubes
Juliet M. Hahn, Ruibo Li, Christopher Brammer, Donna J. Nelson
Synthesis and characterization of new chiral mono- and di-imide atropisomers
Weijun Niu, Ken D. Shimizu
A high-throughput screen for synthetic riboswitches
Sean A. Lynch, Shawn K. Desai, Justin P. Gallivan
Synthesis of oligomers by template-directed olefin metathesis
Daniela Lanari, Ken C-F. Leung, Alshakim Nelson, Stuart J. Cantrill, J. Fraser Stoddart, Robert H. Grubbs
Development of coenzyme-imprinted molecularly imprinted polymers as enzyme-mimetic oxidation catalysts
Andrew J Robak, Bruce P. Branchaud

Symposium Grid -- Division of Organic Chemistry -- Session Listing

The 231st ACS National Meeting, Atlanta, GA, March 26-30, 2006