I&EC 10 |
| The aim of this International Association of Chemical Thermodynamics /International Union of Pure and Applied Chemistry project was to initiate systematic studies on the thermodynamic and thermophysical properties of Ionic Liquids (IL) in order to establish reference quality data for IL's and IL + liquid mixtures. There has been much scatter in the literature data for ionic liquids and their mixtures. The techniques developed for measurements on these standard reference systems should serve as a guide for other researchers in establishing reliable operating procedures and handling techniques with these fluids. The project committee members selected 1-hexyl-3-methylimidazolium bistriflate amide as the reference material and a stock was prepared and purified samples of known water content were distributed to the participants. Measurements made on the pure fluid include: heat capacity, viscosity, density, thermal conductivity, electrical conductivity, speed of sound, relative permittivity, TGA (in nitrogen and air), DSC, and melting point. Mixture properties include: gas solubility (low, medium and high solubility gases including supercritical fluids), liquid-liquid equilibria, vapor-liquid equilibria, infinite dilution activity coefficients, enthalpy of dilution, speed of sound, density and excess volumes. A summary of the measurements undertaken and the progress of the project will be presented. |
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Ionic Liquids: Not Just Solvents Anymore OR Ionic Liquids: Parallel Futures (Sponsored by Green Chemistry and Engineering, Separation Science and Technology and Novel Chemistry with Industrial Applications Sub-Divisions)
8:15 AM-12:25 PM, Sunday, 26 March 2006 Georgia World Congress Center -- B314, Oral
Division of Industrial and Engineering Chemistry |