ORGN 569 |
| Previous studies in our laboratory have shown that allyl-indium metal organometallic complexes add 1,2- to propargyl aldehydes. Studies have also shown that these systems may rearrange via a Cope pathway to give an alpha, beta-unsaturated aldehyde as shown in Scheme 1. In an effort to increase the efficiency of the Cope rearrangement, 1,3-dihalopropene moieties were utilized as nucleophilic species in the system. Introduction of the dihalo species resulted in the formation of a substituted benzene structure when NMF was chosen as the solvent. These reactions, along with the mechanistic pathways of their formation,will be discussed.
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Heterocycles, Aromatics, Metal-Mediated Reactions and Syntheses, Materials, Devices, and Switches
8:00 PM-10:00 PM, Wednesday, 29 March 2006 Georgia World Congress Center -- Ex. Hall B4, Poster
Division of Organic Chemistry |
