ORGN 119 |
| To address the issue of whether the [2+2] cycloaddition products from cyclopentyne are the result of [2+1] cycloaddition to a cyclopropylcarbene followed by ring expansion or by a direct process of the classical [2+2] variety, spiro[2,3]hexan-4-one is prepared and used as the penultimate precursor for a novel type of probe for defining the nature of cyclopentyne and its [2+2] cycloadducts. The results of this study will be discussed.
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Asymmetric Reactions and Syntheses, Physical Organic Chemistry, Combinatorial Chemistry, Total Synthesis
8:00 PM-10:00 PM, Sunday, 26 March 2006 Georgia World Congress Center -- Ex. Hall B4, Poster
Division of Organic Chemistry |
