Synthesis and photoproperties of quinoxalines and phenazines

ORGN 60

Shaobin Miao, Carlito Bangcuyo, and Uwe H. F. Bunz, uwe.bunz@chemistry.gatech.edu. School of Chemistry and Biochemistry, Georgia Institute of Technology, 770 state street, Atlanta, GA 30332
In efforts to prepare better organic semiconductors, we have synthesized phenazines and quinoxalines. Different synthetic strategies were used to provide the aromatic heterocyclic compounds. Condensation of amino compounds with Bis(triisopropylsilylethynyl)dione yielded the quinoxalines. Coupling of bromophenazine with dimethylbutyne provided octabutynylphenazines. All compounds were fully characterized and X-ray single crystal structures were provided. The photoproperties of those compounds were measured as well and proved to be the good metal sensor.
 

Heterocycles and Aromatics
1:00 PM-5:20 PM, Sunday, 26 March 2006 Georgia World Congress Center -- C301, Oral

Division of Organic Chemistry

The 231st ACS National Meeting, Atlanta, GA, March 26-30, 2006