Bis-triptych molecules from tris(1,3-dihydroxy-2-propyl)amine

ORGN 542

Peter Livant, livanpd@auburn.edu, Yuanping Jie, jieyuan@auburn.edu, and Thomas C. Shehee, sheheth@auburn.edu. Department of Chemistry and Biochemistry, Auburn University, Auburn, AL 36849
Amine 2 may be thought of as a "doubled" analogue of triethanolamine, 1. Just as 1 reacts with a variety of nonmetal-containing reagents to form triptych compounds (or atranes), 2 reacts with such compounds to form "bis-triptych" structures, in addition to ordinary triptych structures. X-ray crystal structures of triptych and bis-triptych compounds of the type shown will be presented and discussed in terms of bonding theory. Some chemistry of these new compounds will be discussed.

 

Heterocycles, Aromatics, Metal-Mediated Reactions and Syntheses, Materials, Devices, and Switches
8:00 PM-10:00 PM, Wednesday, 29 March 2006 Georgia World Congress Center -- Ex. Hall B4, Poster

Sci-Mix
8:00 PM-10:00 PM, Monday, 27 March 2006 Georgia World Congress Center -- Ex. Hall B4, Sci-Mix

Division of Organic Chemistry

The 231st ACS National Meeting, Atlanta, GA, March 26-30, 2006