ORGN 504 |
| The versatile, halogenated, fused-ring sydnones 2 and 3 have been prepared in good yields by treatment of iminophosphorane 1 with the appropriate isocyanate or isothiocyanate. The utility of 2 and 3 for Suzuki and Sonogashira couplings has been explored. Further, the ability of the iodosydno[3,4-a]quinoxaline 3 to undergo metal –halogen exchange (with BuLi) and subsequent reaction with electrophiles will be discussed |
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Heterocycles, Aromatics, Metal-Mediated Reactions and Syntheses, Materials, Devices, and Switches
8:00 PM-10:00 PM, Wednesday, 29 March 2006 Georgia World Congress Center -- Ex. Hall B4, Poster
Division of Organic Chemistry |