Cleavage of poly-His tags: Applying protein-protein interactions to promote proper structure

ORGN 391

I-San Chan, isan_chan@hotmail.com, Anna V. Fedorova, afedorov@utm.utoronto.ca, and Jumi A. Shin, jshin@utm.utoronto.ca. Department of Chemistry, University of Toronto, 3359 Mississauga Road, Mississauga, ON L5L1C6, Canada
The poly-His tag is often expressed on fusion proteins to aid in protein isolation and purification. However, the poly-His tag can also lead to misfolding and low protein solubility. We have found that cleavage of poly-His tags is impeded by protein secondary structures. Our bZIP proteins form a dimeric coiled-coil structure. Taking advantage of this fact, we have designed a short peptide as a dimerization agent to target structure subdomains. This alternative strategy has allowed enterokinase to perform efficient proteolysis of the poly-His tags.
 

New Reactions and Methodology, Bioorganic Chemistry, Molecular Recognition and Self Assembly
8:00 PM-10:00 PM, Tuesday, 28 March 2006 Georgia World Congress Center -- Ex. Hall B4, Poster

Sci-Mix
8:00 PM-10:00 PM, Monday, 27 March 2006 Georgia World Congress Center -- Ex. Hall B4, Sci-Mix

Division of Organic Chemistry

The 231st ACS National Meeting, Atlanta, GA, March 26-30, 2006