ORGNWednesday, 31 August 2005
8:00 AM-12:00 PM Washington DC Convention Center -- Ballroom B, Oral
New Reactions and Methodology
Presiding:Robert J. Hinkle
8:00 AM493In situ generation of o-iodoxybenzoic acid (IBX) and the catalytic use of it in oxidation reactions in presence of Oxone® as a co-oxidant
Arun P. Thottumkara, Michael S. Bowsher, Thottumkara K. Vinod
8:20 AM494Spirodiepoxides: Applications and mechanisms
Lawrence J. Williams
8:40 AM495ipso-Hydroxylation of arylboronic acids to phenols using solid H2O2 complexes
G. K. Surya Prakash, Sujith Chacko, Chiradeep Panja, Thomas Mathew, George A. Olah
9:00 AM496A new generation of modular nucleophilic glycine equivalents: Towards the truly practical asymmetric synthesis of alpha-amino acids under operationally convenient conditions
Trevor K. Ellis, Vadim A. Soloshonok
9:20 AM497Metalated nitriles: Diastereoselective alkylations of acyclic nitriles
Fraser F. Fleming, Wang Liu, Omar W. Steward
9:40 AM498Further utilization of mucohalic acids in Lewis acid-catalyzed Knoevenagel-aldol and Friedel-Crafts reactions
Ji Zhang, Koushik Das Sarma, Peter G. Blazecka, Paul Angell, Timothy T. Curran, Daniel Belmont, James G. Davidson
10:00 AM499Novel biocatalytic deacylation reactions in ionic liquids
Vineet Kumar, Ashok K. Prasada, Virinder S. Parmara, Sanjay V. Malhotra
10:20 AM500Electrophilic fluorocyclization vs. electrophilic fluorodesilylation
Mª Carmen Pacheco, Véronique Gouverneur, Susan Wilkinson
10:40 AM501Complexity via 2-pyridone photocycloaddition
Peiling Chen, Scott McN. Sieburth
11:00 AM502Novel covalent reversible reaction between pyrazolotriazinones and keto compounds for the generation of dynamic combinatorial libraries
S. Graciela Mahler, Peter Wipf
11:20 AM503Synthesizing (+)-crobarbatic acid: Preparing furanones by anodic oxidative cyclization
John D. Brandt, Kevin D. Moeller
11:40 AM504Alternative reaction designs for catalytic asymmetric polypropionate construction
Scott G Nelson

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The 230th ACS National Meeting, in Washington, DC, Aug 28-Sept 1, 2005