CHED 215 |
| Two classic chiral amines, Enders' RAMP (1) and Rossiter's S-MAPP(2), have been used as non-transferable ligands in organocuprate conjugate additions for the addition of n-butyl and methyl to chalcone and 2-cyclohexenone. These results will be compared to their silylated analogues 3, 4. Enantiomeric excesses of 90% and nearly quantitative chemical yields were observed in some cases for the silylated analogues.
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Undergraduate Research Poster Session: Organic Chemistry
2:00 PM-4:00 PM, Monday, 29 August 2005 Washington DC Convention Center -- Hall A, Poster
Division of Chemical Education |
