ORGN 399 |
The reaction mechanism for the formation of cyclopentadienones through the coupling of carbene complexes and alkynes has been investigated computationally at the B3LYP 6-31G* level. Interesting mechanistic features have been realized and marked differences relative to a related process, the Dötz reaction, have been noted. The relative energetics of several hypothetical reaction pathways will be discussed.
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Bioorganic, Metal-Mediated Reactions, and Molecular Recognition
8:00 PM-10:00 PM, Tuesday, 30 August 2005 Washington DC Convention Center -- Hall A, Poster
Division of Organic Chemistry |