ORGN 283 |
| The halogen-metal exchange reaction is the most general approach for the preparation of functionalized organometallics. We will describe novel methods allowing to catalyze these exchange reactions allowing a very efficient preparation of a broad range of polyfunctional Mg-organometallic reagents. Applications to the synthesis of polyfunctionalized arynes and addition reactions of heteroatomic nucleophiles to these reactive intermediates will be shown. |
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Arthur C. Cope Award and Arthur C. Cope Scholar Awards
8:00 AM-12:10 PM, Tuesday, 30 August 2005 Washington DC Convention Center -- Ballroom C, Oral
Division of Organic Chemistry |