ORGNMonday, 14 March 2005

1:00 PM-5:00 PM Convention Center -- Room 11A, Oral
Asymmetric Reactions and Syntheses
Presiding:Patrick J. Walsh
1:00 PMKinetic resolution of chiral oxazolidinones via catalytic, enantioselective N-acylation
Vladimir B. Birman, Eric W. Uffman
1:20 PM2,3-Dihydroimidazo[1,2a]quinolines: The second generation of asymmetric acylation catalysts
Vladimir B. Birman, Hui Jiang
1:40 PMSynthesis of sphinganine analogs with conformationally restricted headgroups
Ann M. Dougherty, Frank E. McDonald, Dennis C. Liotta
2:00 PMEfficient stereoselective synthesis of 1-deoxysphingolipid analogs
John M. Wiseman, Frank E. McDonald, Dennis C. Liotta
2:20 PMAsymmetric synthesis of trans-2-substituted 3-amino- and 3-hydroxy-1,2,3,6-tetrahydropyridines and of tetrahydropyrroloimidazoles
Alexandre Lemire, Daniel Beaudoin, André B. Charette
2:40 PMEnantioselective formal hydration of α,β-unsaturated imides by Al-catalyzed conjugate addition of oxime nucleophiles
Christopher D. Vanderwal, Eric N. Jacobsen
3:00 PMDesigning catalysts for the asymmetric epoxidation of alkenes
Declan Gilheany, Matthias Vögler
3:20 PMOrganocatalytic enantioselective synthesis of metabotropic glutamate receptor ligands
Carlos F. Barbas III, Jeff T. Suri, Derek D. Steiner
3:40 PMOrganocatalytic asymmetric addition to multiple bonds
Marco Bella, Steen Saaby, Karl Anker Jørgensen
4:00 PMDesymmetrization by metathesis, producing enantioenriched P-stereogenic phosphine oxides
Fabrice Bisaro, Véronique Gouverneur
4:20 PMP-chirogenic MOP phosphines: The crystal structures of oxides, reduction studies and alternate syntheses
Lee John Higham, Eoin F Clarke, Declan G. Gilheany
4:40 PMKinetic resolution of racemic hydroperoxides by means of an enantioselective reduction
Jason R. Harris, Tom G. Driver, Keith A. Woerpel

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The 229th ACS National Meeting, in San Diego, CA, March 13-17, 2005