ORGN 719 |
| The ability of small molecules to form reversible polymeric structures through noncovalent self-assembly creates an avenue for the rational, molecular design of new, responsive materials. Rational design will require a knowledge of the interplay between the mechanics, kinetics, and thermodynamics of the self-assembly process. Here we report the use of dynamic force spectroscopy to characterize the mechanics and dynamics of coordination bonds used in creating a novel class of reversible polymers. The experiments highlight the importance of molecular dynamics and mechanism, rather than equilibrium thermodynamics, as a determinant of mechanical properties. |
|
Asymmetric Reactions, Molecular Recognition, Self Assembly, Bioorganic Chemistry, Process R&D
8:00 PM-10:00 PM, Wednesday, 16 March 2005 Convention Center -- Hall D, Poster
Division of Organic Chemistry |