Functional macrocycles and oligomers from 1,4-triazoles

ORGN 718

Hemraj Juwarker and Stephen L. Craig, stephen.craig@duke.edu. Department of Chemistry, Duke University, Box 90346, Durham, NC 27708
Regioselective formation of 1,4-triazoles from m-phenyldiacetylenes and m-phenyldiazides via Huisgen 1,3-dipolar cycloadditions are facile reactions for the synthesis of functional macrocycles and oligomers. Both the cyclic and linear species offer promise as hosts for anion binding and as modules for pi-stacked aggregates. The synthesis of these compounds and their anion binding properties are reported.
 

Asymmetric Reactions, Molecular Recognition, Self Assembly, Bioorganic Chemistry, Process R&D
8:00 PM-10:00 PM, Wednesday, 16 March 2005 Convention Center -- Hall D, Poster

Sci-Mix
8:00 PM-10:00 PM, Monday, 14 March 2005 Convention Center -- Sails Pavilion, Sci-Mix

Division of Organic Chemistry

The 229th ACS National Meeting, in San Diego, CA, March 13-17, 2005