ORGN 35 |
| Rhodium and palladium complexes are excellent catalysts for the highly regio-, stereo-, and enantioselective reactions. This presentation will include some industrially interesting reactions including the hydroformylation of unsaturates, the synthesis of amino acid derivatives by a sequence of double carbonylation/imine formation/hydrogenation reactions, and the cyclocarbonylation of halophenols, thiols, and anilines. Dynamic kinetic resolution in the reaction of heterocycles with heterocumulenes proceeds in high enantiomeric excess to give 5-7 membered ring bi-and polycyclic products |
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Current Aspects of Synthetic Organic Chemistry
1:10 PM-5:00 PM, Sunday, 13 March 2005 Convention Center -- Ballroom 20A-B, Oral
Division of Organic Chemistry |