ORGNMonday, August 23, 2004

1:00 PM-5:00 PM Pennsylvania Convention Center -- 201A, Oral
Asymmetric Reactions and Syntheses
Presiding:Lee H. Latimer
1:00 PM Iridium-catalyzed allylic amination reactions
Andreas Leitner, John F. Hartwig
1:20 PM Nitroso aldol synthesis of enamine
Norie Momiyama, Hiromi Torii, Susumu Saito, Hisashi Yamamoto
1:40 PM Catalytic asymmetric diboration: Functionalization of enantiopure alkyl 1,2-bis(boronates)
Jeremy B Morgan, James P. Morken
2:00 PM Regioselective and divergent opening of vinyl epoxides with ethoxyacetylene
Per Restorp, Peter Somfai
2:20 PM Asymmetric allylation of ketone and aldehyde enolates via Claisen-type rearrangements
Jon A. Tunge, Erin C. Burger
2:40 PM Asymmetric Lewis acid-mediated [2,3]-sigmatropic rearrangement of allylic α-amino amides
Jan Blid, Peter Somfai, Peter Brandt
3:00 PM Following an ISES lead: First asymmetric Ni-mediated allylic amination
David B. Berkowitz, Gourhari Maiti
3:20 PM Enantioselective synthesis of "quaternary" 1,4-benzodiazepin-2-ones: Extension of a privileged scaffold
Paul R. Carlier, Hongwu Zhao
3:40 PM Persistence of chiral memory in enantioselective deprotonation/alkylation of 1,4-benzodiazepin-2-ones
Paul R. Carlier, Polo C H. Lam
4:00 PM A memory of chirality route to enantioenriched quaternary 1,4-benzodiazepin-2,5-diones
Paul R. Carlier, Stephanie MacQuarrie
4:20 PM Substituent effects in memory of chirality deprotonation/trapping sequences of 1,4-benzodiazepin-2-ones
Paul R. Carlier, Joseph C. DeGuzman, Hongwu Zhao, Danny C. Hsu
4:40 PM Optical activity ex machina: Absolute asymmetric separation
Roman Bielski, Michal Tencer

Previous Session -- Asymmetric Reactions and Syntheses

Symposium Grid -- Division of Organic Chemistry -- Session Listing

The 228th ACS National Meeting, in Philadelphia, PA, August 22-26, 2004