ORGNSunday, August 22, 2004

8:00 PM-10:00 PM Pennsylvania Convention Center -- Hall D, Poster
Asymmetric Reactions and Syntheses, Metal-Mediated Reactions, Materials, Molecular Recognition
Organizer:Robert D. Larsen
Synthesis and catalytic competency of a novel dicationic phase transfer catalyst
Darren K. MacFarland, Michelle E. Rueffer, Linda K. Fort
Direct observation of enantioselective cooperativity at trimetallic centers
Jian Gao, Ralph A. Zingaro, Joe H. Reibenspies, Arthur E Martell
Synthesis of tin hydride-cyclodextrin
Fernando Ortega-Caballero, Mikael Bols
New chiral camphor-based 1,4-amino alcohols as ligands for purposes of asymmetric synthesis
Urvi Sheth, Vesa Nevalainen
Design and synthesis of new beta-aminoalcohol catalysts for the addition of Et2Zn to aldehydes via a quantitative structure selectivity relationship (QSSR) protocol
Venkatachalam Annamalai, James Ianni, Puay Wah Phuan, Marisa C. Kozlowski
A new class of chiral P,N-ligands and their application towards asymmetric catalysis
Regina C. So, Mukund P. Sibi
Synthesis of chiral 1,3-oxazin-2-ones from carbohydrate derivatives
Jean Rene Ella-Menye, Vibha Sharma, Guijun Wang
Cis- and trans-(N-sulfinyl)hexahydrobenzoxazolidin-2-ones: New reagents for the asymmetric synthesis of (R)- and (S)-benzylmethylsulfoxide
Cecilia Anaya de Parrodi, Angel Clara-Sosa, Mario Sanchez, Leticia Quintero, Eusebio Juaristi
Phosphine-phosphite and phosphine-phosphinite: New ligands for highly enantioselective asymmetric hydrogenation
Xumu Zhang, Yongjun Yan, Yongxiang Chi
Synthesis of chiral binaphthyl phospholane and phosphepine ligands and their applications in highly enantioselective hydrogenation of beta-amino acid derivatives
Xumu Zhang, Wenjun Tang, Weimin Wang
Asymmetric hydrogenation of functional olefins and ketones with TunePhos–Ru catalysts
Xumu Zhang, Shulin Wu, Wenjun Tang, Aiwen Lei, Minsheng He
Rhodium and ruthenium catalyzed enantioselective transfer hydrogenation of α,β-unsaturated carboxylic acids
David M. Tellers, Claire Oakley, J. Chris McWilliams, Yongkui Sun
Asymmetric synthesis of 1,3,4-trisubstituted pyrrolidines
Kevin Belyk, Charlotte Beguin, Michael Palucki, Minal Patel, Jimmy O. Dasilva, David Askin, Nobuyoshi Yasuda
Paper Withdrawn
Alpha-Trialkylsilyl amino acids: Preparations and applications
Guodong Liu, Scott McN. Sieburth
A facile method for the incorporation of alkyl groups in polyol natural products
Matthew S. Mortensen, Md. Moinuddin Ahmed, George A. O'Doherty
Asymmetric alkylation with salen catalysts containing Lewis acid and Lewis base moieties
Michael W. Fennie, Erin F. DiMauro, Venkatachalam Annamalai, Erin M. O'Brien, Marisa Kozlowski
A synthetic approach towards halichlorine using a N-bromosuccinimide-promoted ring expansion reaction as the key step
Gregory R Dake, Paul B Hurley
Stereocontrolled synthesis of the trans-3,4-dimethyl-4-(3-hydroxyphenyl)piperidine opioid antagonist alvimopan
Bertrand Le Bourdonnec, Roland E. Dolle
Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex
Yong Chua Teo, Teck Peng Loh
Towards the asymmetric total synthesis of Fusicoccin A
Vyjayanthi N Kambam, Scott McN. Sieburth
Enantioselective diethylzinc additions to aldehydes catalyzed by chiral ligands with fluxional groups
Levi Stanley, Mukund P. Sibi
Catalytic asymmetric vinylation of ketones
Hongmei Li, Patrick J. Walsh
Catalytic asymmetric allylation of ketones and cyclic enones: Tandem diastereoselective epoxidation with TBHP or sequential oxy-Cope rearrangement
Jeung Gon Kim, Karen M. Waltz, Iliana Garcia, Patrick J. Walsh
AEI: Diastereoselective nucleophilic additions to 2-keto-4-methyl-1,3-dioxanes: 1,3-Dioxanes as chiral auxiliaries
Daniel R. Clark, William F. Bailey
Total synthesis of (-)-normalindine via the addition of metallated 4-methyl-3-cyanopyridine to an entantiopure sulfinimine
Franklin A. Davis, Jeffrey Y. Melamed, Steve S. Sharik
Diastereoselective indium-mediated allylation of chiral hydrazones
Gregory R. Cook, Bikash Maity, Robert Kargbo
Lewis acid-mediated enantioselective reaction of nitrones
Zhihua Ma, Mukund P. Sibi, Craig P. Jasperse
Chiral Lewis acid catalysis in nitrile oxide cycloadditions
Kennosuke Itoh, Mukund P. Sibi, Craig P. Jasperse
Anti-selective aldol reactions of N-glycolyloxazolidinethiones with acetaldehyde: Synthesis of the de-oxygenated sugars of apoptolidin
Michael T. Crimmins, Alan Long
2-tert-Butyl-3-methyl-2,3-dihydroimidazol-4-one-N-oxide: A new nitrone-based chiral glycine equivalent
Steven W. Baldwin, Alan Long
Highly enantioselective copper-catalyzed conjugate addition of diethylzinc to nitroalkenes
Hojae Choi, Zihao Hua, Iwao Ojima
Stereoselective radical and Heck cyclizations of axially chiral anilides with transfer of axial chirality to newly formed stereocenters
Andre J. B. Lapierre, Dennis Curran
Enantioselective desymmetrisations: The first intermolecular Suzuki couplings producing stereodefined sp3 carbon centres
Luke H. W. Powell, Michael C. Willis
A practical synthesis of D-erythro-Sphingosine using a cross-metathesis approach
Staffan Torssell, Peter Somfai
Expanded substrate scope of enantioselective ring-closing metathesis using an improved ruthenium alkylidene catalyst
Timothy W. Funk, Jacob M. Berlin, Robert H. Grubbs
Recent developments in dynamic kinetic resolution of alcohols employing a ruthenium racemization catalyst together with an enzyme
Belén Martín–Matute, Michaela Edin, Krisztián Bogár, Jan E. Bäckvall
(S)-Selective dynamic kinetic resolution of secondary alcohols by combination of subtilisin and an aminocyclopentadienylruthenium complex as the catalysts
Han Ki Lee, Mahn Joo Kim
Remote functionalization of trienoates by Sharpless catalytic dihydroxylation: Towards the synthesis of colletol
Dennis J Tomcik, Thomas J. Hunter, George A. O'Doherty
One-pot synthesis of epoxy alcohols via tandem addition-epoxidation with dioxygen
Ann Kelly, Alice E. Lurain, Aaron G. Maestri, Patrick J. Walsh
One-pot asymmetric synthesis of acyclic epoxy alcohols via tandem vinylation-epoxidation with dioxygen
Alice E. Lurain, Patrick J. Carroll, Patrick J. Walsh
Osmium/palladium approach to the synthesis of 1,3-polyols: Toward the construction of polyol containing natural products
Joseph M. Dougherty, Thomas J. Hunter, George A. O'Doherty
Asymmetric synthesis of (R)-(+)-4-aminocyclo-pentenone using olefin-enone ring-closing metathesis (RCM)
Franklin A. Davis, Yongzhong Wu
2H-Azirine 3-phosphonates: Regioselective oxidation of NH aziridine phosphonates
Franklin A Davis, Tokala Ramachandar, Yongzhong Wu
Rhodium-catalyzed enantioselective diboration of unactivated alkenes
Jeremy B Morgan, James P. Morken
New applications of the asymmetric reductive aldol reaction and the reductive Claisen rearrangement in natural product synthesis
Nathan O. Fuller, James P Morken
De-novo synthesis of branched and linear mixed D/L oligosaccharides
Satheesh Babu Ravula, Maoquan Zhou, George A. O'Doherty
De novo synthesis of phenol, flavone and coumarin glycosides
Satheesh Babu Ravula, Sanjeeva R Guppi, George A. O'Doherty
Enantioselective syntheses of phomopsolide E and analogs
Miaosheng Li, George A. O'Doherty
Enantioselective synthesis of (+)-epi-anamarine
Dong Gao, George A. O'Doherty
Design and synthesis of antimalarial agents based on Manzamine A
Allyn T. Londregan, Justin Ragains, Jeffrey D. Winkler
Metalations facilitated by hydrocarbon solvents: Activation provided by opposing-p-resonance in aryl substrates
D. W. Slocum, Melody Taylor, Scott Brown, Seth Dumbris, B. D. Woosley, Phillip Shelton, R. W. Holman
Vitamin D side chain triazole analogs via cycloaddition "click" chemistry
Byung Chul Suh, Heung Bae Jeon, Gary H. Posner, Steven M. Silverman
Catalytic carbometalation of alkynes by cationic chromium(III) complexes
Gary A. Molander, Erin M. Sommers
Highly diastereoselective synthesis of (Z)-1-chloro-1-trimethylsilyl -1-alkenes
Narayan G. Bhat, Edmundo Lozano
Novel synthesis of (E)- gem-dimetalloalkenes containing boron and germanium
Narayan G. Bhat
Synthesis of reduced polypropionates via Zr-catalyzed asymmetric C-C bond formation
Bo Liang, Ze Tan, Ei ichi Negishi
One-pot Zr-catalyzed asymmetric carboalumination- Pd-catalyzed cross-coupling tandem process: Its application to the syntheses of siphonarienes and borrelidin
Tibor Novak, Ei ichi Negishi
Synthesis and applications of new phosphine oxazoline ligands
Xumu Zhang, Duan Liu, Qian Dai
Rh-catalyzed asymmetric hydrogenation of amino ketones with an electron-donating P-chiral bisphosphine ligand
Xumu Zhang, Duan Liu
Enantioselective organic transformations via organoaluminum catalysis
Christopher R. Graves, SonBinh T. Nguyen
Paper Withdrawn
Oxidation of dirhodium(II) caprolactamate: Preparation, characterization, and synthetic applications
Arthur J. Catino, Michael P. Doyle
Synthesis of bicylclic pyrrolidines via catalytic ylide chemistry
Darren Bykowski, Ming Yan, John T. Colyer, Wenhao Hu, Luisa S. Gronenberg, Michael P. Doyle
Sequential applications of Lewis acid-catalyzed Mukaiyama aldol reaction and intramolecular C-H insertion: Synthesis of highly substituted cyclobutanones
Michael P. Doyle, Kousik Kundu, Albert E. Russell
Synthesis of chiral tetrahydrofuranones, tetrahydrothiophenones, and azetidinones via rhodium (II)-catalyzed cyclization reactions
Lindsay Odom, Young B. Kim, John M. Rimoldi
Rhodium-catalyzed routes to thioboronate esters
Stephen A. Westcott, Christopher M. Vogels, R. Tom Baker
Synthesis of novel aminoboronic acid derivatives using metal-catalyzed hydroborations
Stephen A. Westcott, Stephen J. Scales, Hanni A. Darwish, Daniel I. McIsaac, Jonathan D. Webb, Christopher M. Vogels
Synthetic and chemical study on the formation of azabicyclo[X.Y.0]alkane amino acids through cyclohydrocarbonylation
Wen Hua Chiou, Iwao Ojima
Ru(III)-catalyzed cyclization of arene-alkene substrates via intramolecular electrophilic hydroarylation
So Won Youn, Dalibor Sames
Intermolecular and intramolecular Pauson-Khand reactions of cyclopropenes
Mahesh K. Pallerla, Joseph M. Fox
Suzuki-Miyaura cross-coupling of potassium organotrifluoroborates
Gary A. Molander, Luciana A. Felix, Daniel E. Petrillo
Heck reaction with phosphite ligands in supercritical carbon dioxide
Jin kyun Lee, A. B. Holmes, Edward J. Bush, Ian McConvey
Total synthesis of furaquinocin A, B and E
Oliver R. Thiel, Barry M. Trost, Hon Chung Tsui
Suzuki reactions of alpha-halo enaminones and the asymmetric synthesis of Ipalbidine
Xin Wang, Brandon J. Turunen, Gunda I. Georg
Palladium(0)–catalyzed cycloisomerization of enallenes
Katja Närhi, Johan Franzén, Jan E. Bäckvall
Formal insertion of 1,2-dienes into palladacycles with a metal-bonded stereogenic carbon: Synthesis of contiguously substituted 3,4-dihydro-2H-1-benzopyrans
Genliang Lu, Helena C. Malinakova
Ligand, copper, and amine-free Sonogashira reactions of aryl iodides with terminal alkynes
Sameer Urgaonkar, John G. Verkade
A novel cascade reaction to ortho-furyl biphenyls
John H. Hilmer, Mahesh K. Lakshman
General synthesis of heteroatom-substituted porphyrins via metal-catalyzed cross-coupling reactions
X. Peter Zhang, Guangyao Gao, Ying Chen
Selective cross coupling and metalation reactions of pyridazinones
Thomas M. Stevenson, Brett A. Crouse, Tho V. Thieu, Cristina Gebreysus, Donna L. Piotrowski
Palladium-catalyzed syntheses of carbonyl containing phenethylamino pyrimidines
Thomas M. Stevenson, Brett A. Crouse
Palladium phosphinous acid-catalyzed cross-coupling reactions in water
Rachel Lerebours, Christian Wolf
N-Heterocyclic carbene-palladium complex on polystyrene resin surface as polymer-supported catalyst and its application in Suzuki cross-coupling reaction
Jong Ho Kim, Yoon Sik Lee
Regioselective Suzuki coupling reactions on pyrroles: Studies and applications
Scott T Handy, Yanan Zhang, Jesse J Sabatini, Inessa Vulfova
Suzuki-Miyaura coupling reactions of 2’-deoxyguanosine O6-arylsulfonates with aryl boronic acids at room temperature
Padmaja Gunda, Mahesh K. Lakshman
Nickel as a replacement for palladium in Suzuki-type cross-coupling reactions
Virgil Percec, Geoffrey M. Golding, Jan Smidrkal, Oliver Weichold
Highly efficient Pd-catalyzed cross-coupling and carbonylative cross-coupling reactions by triorganoindiums and tetraorganoindates
Phil Ho Lee
A robust palladium-catalyzed cyanation procedure: Beneficial effect of zinc acetate
Ramakrishnan Chidambaram
Microwave-assisted N-arylation of a sulfoximine with aryl chlorides
Michael Harmata, Xuechuan Hong
Synthesis and catalytic properties of novel polyfluorinated pincer palladium complexes
Margit J. Jensen, Alexander Kornienko
Indium-mediated Prins cyclization using allyllic silicon as allylating reagent
Kok Ping Chan, Teck Peng Loh
De novo synthesis of galacto-pyranosides and 4-deoxy-pyrano-lactones via an iterative use of Sharpless asymmetric dihydroxylation
Md. Moinuddin Ahmed, Dennis J Tomcik, George A. O'Doherty
LTA-mediated β-oxidative decarbonylation of homoallylic alcohols
Marcelo D. Preite, Andrés E. Pérez Carvajal, Mauricio A. Cuellar
Tribological behavior of epoxy-silsesquioxanes hybrid coating on glass substrate
Xingwen Zhang, Lijiang Hu, Dezhi Sun
Synthesis and electronic properties of novel symmetric spirosilabifluorene derivatives
Sang Ho Lee, Zakya H. Kafafi
Lyotropic liquid crystalline matrices as chiral receptors, molecular sensors and nano-filtration membranes
J. Shailaja, Douglas L. Gin
Synthesis and properties of new dichromophoric sensitizers for TiO2 nanoparticles
Elena Galoppini, Olena Taratula, Miroslav Zabadal
Synthesis and maneuvering of a single molecular nanoscale vehicle: NanoTruck
Yasuhiro Shirai, Yuming Zhao, Andrew J. Osgood, Chiu Yu-Hung, Yuxing Yao, Hanbiao Yang, Lionel Saudan, Kevin F. Kelly, James M. Tour
Synthesis and properties of multifullerene-oligo(phenylene ethynylene) hybrids
Yasuhiro Shirai, Yuming Zhao, Long Cheng, James M. Tour
Nano surgery of C60: The first synthesis of 1,2,3,4,5,6-hexasubstituted C60, a precursor of open C60?
Shih Ching Chuang, Yves Rubin
Organometallic abiotic foldamers
Fan Zhang, Joseph M. Fox
Total synthesis of artificial surfaces
Zhenzhen Dong, Joseph M. Fox
Small molecule models of artificial surfaces
Xiaozhong Liu, Joseph M. Fox
Minimizing purification time with high resolution flash chromatography
David Trail
Development of a fluorescent sensor for enantioselective recognition of chiral compounds
Xuefeng Mei, Christian Wolf
Highly selective colorimetric detection of Fe(II) using a non-natural amino acid as a water-soluble sensor
Shuanglong Liu, Christian Wolf
Synthesis, stereodynamics and some applications of axially chiral 1,8-diquinolylnaphthalenes
Gilbert E. Tumambac, Christian Wolf
Water-soluble fluorescent boronic acid compounds for saccharide sensing: Structural effect on their fluorescence properties
Yanling Zhang, Xingming Gao, Binghe Wang
Polyhedral Oligomeric Silsesquioxane (POSS) units as molecular recognition elements
Joseph B. Carroll, Benjamin L. Frankamp, Sudhanshu Srivastava, Vincent M. Rotello
Mecanochemistry of molecular shuttles based on tetrathiafulvalene units and 1,5-dioxynaphthalene ring systems
Seogshin Kang, Scott Vignon, Brian Northrop, Hsian Rong Tseng, J Fraser Stoddart
On the synthesis of a series of receptors exhibiting endohedral stereochemistry
Jennifer N. Slaughter, Sandro Mecozzi
Self-assembling dendrons based on an AB4 building block
Virgil Percec, Betty C. Won
Self-assembling dendronized ionic-liquids
Mohammad R. Imam, Virgil Percec, V.S.K. Balagurusamy, Mihai Peterca, Paul A. Heiney
Chenodeoxycholic acid-based receptors: Synthesis and anion binding properties
Hong Seok Kim, Ki Soo Kim
A new class of shape-persistent macrocycles: Highly efficient, one-pot macrocyclization assisted by the folding and preorganization of acyclic precursors
Lihua Yuan, Wen Feng, Kazuhiro Yamato, Adam Sanford, Joseph Ferguson, Mingfeng Li, Bing Gong
Self-assembly and molecular recognition of crescent oligoamides
Adam R. Sanford, Lihua Yuan, Wen Feng, Joseph Ferguson, Bing Gong
Synthesis of host molecules based on steroid skeleton: Inclusion behavior toward quaternary ammonium ions
Iizuka Masato, Ito Kazuaki, Morohashi Naoya, Ohba Yoshihiro
Bottom-up construction of pure guanine DNA nanostructures using short oligonucleotide building blocks
Dongsheng Liu, Rachel McKendry, Shankar Balasubramanian
Porphyrin anchored [5]pseudorotaxane, [5]rotaxane and polyrotaxane
Dönüs Tuncel, Nesibe Cindir, Yasar Akdogan
Synthesis of chelators based on 1,10-phenanthroline for use as immunoassay reagents
Zheying Zhu, Qiang Guo, Harry E. Ensley
Thermally controllable ß-hairpin hydrogels using hydrophobic content to control folding and self-assembly
Christopher M. Micklitsch, Joel P. Schneider
Light-triggered self-assembly of beta hairpin peptides to hydrogels
Lisa A. Haines, Joel P Schneider
Conformational switching in a new family of water-soluble peptoid oligomers
Sung B. Y. Shin, Kent Kirshenbaum
ESR structural studies of double spin labeled peptoid helices
Aaron T Fafarman, Barney Yoo, Peter P. Borbat, Jack H. Freed, Kent Kirshenbaum
Synthesis of 310 helix-inducing constrained analogues of L-Proline
Gianluca Papeo, Stephen Hanessian, Kamal Fettis
Amidocavitands for the recognition of helical peptides and as building blocks for rod shaped molecular container compounds
Ashim J. Thakur, Ralf Warmuth

Symposium Grid -- Division of Organic Chemistry -- Session Listing

The 228th ACS National Meeting, in Philadelphia, PA, August 22-26, 2004