Synthesis and applications of new phosphine oxazoline ligands

ORGN 134

Xumu Zhang, Duan Liu, and Qian Dai. Department of Chemistry, The Pennsylvania State University, 152 Davey Lab, University Park, PA 16802
Several new P, N ligands were synthesized from commercially available phenylglycinol. Here we want to report their application in the Ir-catalyzed asymmetric hydrogenation of unfunctionalized olefins. The application of this system in other transition metal catalyzed reactions will also be described.

 

Asymmetric Reactions and Syntheses, Metal-Mediated Reactions, Materials, Molecular Recognition
8:00 PM-10:00 PM, Sunday, August 22, 2004 Pennsylvania Convention Center -- Hall D, Poster

Division of Organic Chemistry

The 228th ACS National Meeting, in Philadelphia, PA, August 22-26, 2004