ORGN 189 |
Self-assembling dendronized ionic-liquids
| Mohammad R. Imam1, Virgil Percec1, V.S.K. Balagurusamy2, Mihai Peterca2, and Paul A. Heiney2. (1) Department of Chemistry, University of Pennsylvania, 231 S. 34th Street, Philadelphia, PA 19104, (2) Department of Physics and Astronomy and Laboratory for research on the Structure of Matter, University of Pennsylvania, Philadelphia, PA 19104 |
| Self-assembling dendronized ionic-liquids containing triethyl and tripropyl ammonium, pyridinium and 3-methylimidazolium chloride, tetrafluoroborate and hexafluorophosphate at their apex were synthesized. These minidendrons self-assemble into supramolecular cylindrical or spherical dendrimers at elevated to room temperature ranges, which in turn self-organize into 2-D hexagonal or 3-D cubic liquid crystalline lattices. Their structural and retrostructural analysis has demonstrated the first examples of ionic liquid mediated self-assembly of columnar and spherical supramolecular dendrimers containing columnar and spherical nanoscale ionic liquid reactors segregated in their core. 
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Asymmetric Reactions and Syntheses, Metal-Mediated Reactions, Materials, Molecular Recognition
8:00 PM-10:00 PM, Sunday, August 22, 2004 Pennsylvania Convention Center -- Hall D, Poster
Sci-Mix
8:00 PM-10:00 PM, Monday, August 23, 2004 Pennsylvania Convention Center -- Hall D, Sci-Mix
Division of Organic Chemistry
The 228th ACS National Meeting, in Philadelphia, PA, August 22-26, 2004
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