| ORGN | Sunday, March 28, 2004 | ||
8:00 PM-10:00 PM Anaheim Convention Center -- Hall A, Poster | |||
New Reactions and Methodology, Metal-Mediated Reactions, Heterocycles and Aromatics | |||
| Organizer: | Robert D. Larsen | ||
| 46 | A concise synthesis of (-)-cytoxazone via regioselective and stereoselective introduction of amino group using chlorosulfonyl isocyanate Ji Duck Kim, In Soo Kim, Cheng Hua Jin, Young Hoon Jung | ||
| 47 | Studies on the construction of vinyl-substituted adjacent quaternary centers by photochemical decarbonylation of crystalline ketones Christopher J. Mortko, Miguel A. Garcia-Garibay | ||
| 48 | Synthesis of enaminoketones using imidoylbenzotriazoles and silyl enol ethers Amy E. Hayden, Kostyantyn Kirichenko | ||
| 49 | Stereoselective preparation of b-hydroxy-b-trifluoromethyl ketones and a,b-dihydroxy-b-trifluoromethyl ketones, using chiral (L) proline as a catalyst G. K. Surya Prakash, Chiradeep Panja, Mihirbaran Mandal, Hiriyakkanavar Ila, George A. Olah | ||
| 50 | Ipso-Nitration of arylboronic acids: Chlorotrimethylsilane-nitrate salt as an efficient reagent system G. K. Surya Prakash, Chiradeep Panja, Vijayalakshmi Surampudi, Nicos A. Petasis, Thomas Mathew, George A. Olah | ||
| 51 | New exo/endo selectivity observed in monohydrolysis of dialkyl bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylates Satomi Niwayama, Yoshikazu Hiraga | ||
| 52 | Synthesis of substituted 3-(triisopropylsilyl)-2-naphthols Hélène Juteau, Yves Gareau, Hugo Lachance | ||
| 53 | Synthetic applications of vinyl tris(trimethylsilyl)silanes Pedro I. Garcia Jr., Zhizhong Wang, Stanislaw F. Wnuk | ||
| 54 | Synthesis and synthetic utility of pyrrole carbinols: Versatile intermediates in organic synthesis Darren J. Dixon, Mark S. Scott | ||
| 55 | Reaction of 1-N-SES-2,2-dimethylaziridine with aryl Grignards provides an expedient route to 2-aryl-1,1-dimethylethylamine derivatives Leland O. Weigel, Michael B. Rice, Andrew M. Ratz | ||
| 56 | Paper Withdrawn | ||
| 57 | Synthesis of O-alkyl oximes Debra D. Dolliver, David B. Delatte, Joshua Austin, James E. Johnson, Jeffrey E. Rowe, Simon G. Bott, Diana C. Canseco | ||
| 58 | Functionalized alkenes from epoxides David M. Hodgson, Matthew J. Fleming | ||
| 59 | Radical cyclizations of vinylboranes with EPHP M. Mark Midland, Diane Hinkens | ||
| 60 | Novel uses of amino carbinols and amino alkoxides as intermediates in synthesis Darren J. Dixon, Amanda C. Lucas | ||
| 61 | Ynamide survivability: Studies toward the synthesis and reactivity of functional groups with ynamides Kai-Hao Tung, Kimberly Kurtz, Richard P. Hsung | ||
| 62 | The study of alkoxide-promoted enyne-allene cyclizations: Next generation isolated alkenes Michelle K. Waddell, Mark A. Lipton | ||
| 63 | Design of a new sterically hindered 1,1-dimethylallyl ester as a new protecting group for carboxylic acids Minoo Sedighi | ||
| 64 | Microwave-assisted amide synthesis on silica-supported carbodiimide Shahnaz Ghassemi, Peter. C. Rahn | ||
| 65 | Functionalization of crosslinked polystyrene nanospheres G. K. S. Prakash, Ryan Desousa, Geroge A. Olah | ||
| 66 | Developments of environmentally friendly organic transformations Shui-Ling Chen, Teck-Peng Loh | ||
| 67 | To improve the experimental system and upgrade the experimental capability Lin-Hua Song, Cui-Yu Jiang | ||
| 68 | Activation amines in anion-radical condensation with aromatic ketyles Dilbar A. Turaeva, Yu V. Kurbatov | ||
| 69 | New reagents for organic synthesis: Imidazolium dichromate/alumina as a mild and efficient heterogeneous system for cleavage of C=N Surya K De | ||
| 70 | DCC/DMAP-mediated coupling of carboxylic acids with oxazolidinones and thiazolidinethiones Carlos Kleber Zago Andrade, Rafael Oliveira Rocha, Otilie Eichler Vercillo, Wender Alves Silva, Ricardo Alexandre Figueiredo Matos | ||
| 71 | Unique microwave-assisted oxidations of carbamates and analogs utilizing an air stable dichloro-iodobenzene reagent Walter Salamant, Christopher Hulme | ||
| 72 | Novel LDA-mediated rearrangement of 2,2-bis(alkylsulfonyl)-1-phenylethanones: Regiospecific formation of 2-alkylsulfonylmethylsulfonyl-1-phenylethanones Jong Kwan Bin, Jae Sang Lee, Kyongtae Kim | ||
| 73 | Effect of solvent on the lithium - halogen exchange of primary alkyl iodides and aryl bromides Mark R. Luderer, Jason D. Brubaker, Kevin P. Jordan, William F. Bailey | ||
| 74 | Highly diastereoselective synthesis of (E)-1-bromo-1-trimethylgermyl-1-alkenes Narayan G. Bhat, Noe Loredo | ||
| 75 | Novel synthesis of (E)-gem-dimetalloalkenes containing boron and tin Narayan G. Bhat, Nisha Varghese | ||
| 76 | Rhodium-catalyzed [2+2+2+1] cycloaddition reaction: Application to the construction of fused 5-7-5 ring systems from various enediynes Bibia Bennacer, Iwao Ojima | ||
| 77 | Cp*Rh(III)-catalyzed Leuckart-Wallach-type reductive amination of ketones Masato Kitamura, Shinji Tanaka, Tetsuya Mukai, Hajime Saburi | ||
| 78 | Cross-metathesis reaction of vinylchlorins and vinylporphyrins Xin Liu, Ethan Sternberg, David Dolphin | ||
| 79 | Investigating the scope of the ring-closing metathesis reaction in the development of cyclic enol phosphonamidates Stephen R. Sieck, Matthew D. McReynolds, Paul R. Hanson | ||
| 80 | Simple thiazocine-2-acetic acid derivatives via ring-closing metathesis (RCM) Dallas K. Bates, Xiaofen Li, Parag V. Jog | ||
| 81 | Evidence for radical mechanism in olefin metathesis catalyzed by tungsten systems in a low oxidation state Valerian Dragutan, Ileana Dragutan, Mihai Dimonie | ||
| 82 | Radical C-C bond formation in cobalt-propargyl complexes: Stereoselective access to novel nonsteroidal hormones Gagik G. Melikyan, Arthur Florut, Christopher Wild | ||
| 83 | Use of the molybdenum hexacarbonyl-mediated tandem allenic Pauson-Khand reaction for the synthesis of a dicyclo[a,e]pentalene Hui Cao, Judith L. Flippen-Anderson, Jessica L. Chen, James M. Cook | ||
| 84 | Metal-mediated homo [6+2] cycloaddition reactions James H. Rigby, Zeeshan Kamal, Tricia L. May, Mary J. Heeg | ||
| 85 | One-pot, catalytic regio- and stereoselective preparation of (Z)-β-chalcogenyl acrylamides Daniel J. Knapton, Tara Y. Meyer | ||
| 86 | Carbonylative acetylene coupling of aryl diazonium ions with NHC-palladium catalysis Chun Song, Yudao Ma, Merritt B. Andrus | ||
| 87 | Highly active, air-stable combinatorial catalysts for the C-C, C-N, and C-S bond formations via cross-coupling reactions of aryl halides George Y. Li | ||
| 88 | Synthesis of coumestans by selective electrophilic cyclization followed by palladium-catalyzed intramolecular carbonylation: An efficient synthesis of coumestrol Dawei Yue, Richard Larock | ||
| 89 | Novel metal-mediated approaches for the rapid assembly of nitrogen heterocycles Richard H. Blaauw, Sape S. Kinderman, Henk Hiemstra, Bart C.J. van Esseveldt, Floris P.J.T. Rutjes | ||
| 90 | Ferrocene-based palladacyclic precatalysts for C-C bond forming reactions Christopher J. Richards, Francesc X. Roca | ||
| 91 | Palladium-mediated stereospecific synthesis of 3-enynyl substituted thioflavones/flavones via sequential Heck–Sonogashira strategy Manojit Pal, Karuppasamy Parasuraman, Venkataraman Subramanian, Rambabu Dakarapu, Koteswar R. Yeleswarapu | ||
| 92 | Nickel-catalyzed cross-coupling reaction of alkyl arenesulfonates with arylmagnesium bromides Chul-Hee Cho, Tae-Yong Ryoo, Kwangyong Park | ||
| 93 | Organocuprate oxidation with improved functional group tolerance and its application to medium ring synthesis David S. Surry, David R. Spring | ||
| 94 | Copper-catalyzed cross-coupling of aryl acetylenes and vinyl iodides D. Venkataraman, Craig G. Bates, Pranorm Saejueng | ||
| 95 | Mild and practical copper-catalyzed amination of unactivated halothiophenes Zhikuan Lu, Robert J. Twieg | ||
| 96 | Cu-mediated alkoxystannane addition to an allylic lactone: Application to the synthesis of sclerophytin A Matthias C. McIntosh, Christopher M. McFarland, John M. Hutchison, Harriet A. Lindsay | ||
| 97 | Indium-promoted additions to propargyl aldehydes: Mechanistic studies into Michael additions versus Cope rearrangements Thomas M. Mitzel, Annie Troutman | ||
| 98 | In-mediated b-allylation, b-propargylation, and b-allenylation onto a,b-unsaturated ketones: Reactions of in situ generated 3-tert-butyldimethylsilyloxyalk-2-enylsulfonium salts with in situ generated organoindium reagents Phil Ho Lee, Kooyeon Lee | ||
| 99 | Indium-promoted cross coupling reactions of acetylene moieties Thomas M. Mitzel, Kristen M. Allegue | ||
| 100 | Hydrogenation of 2,3-diphenylbutadiene: A revealing kinetic study Xiuhua Cui, Kevin Burgess | ||
| 101 | Expedient deprotection of N-Alloc group using a polymer-supported palladium catalyst in conjunction with a bound borohydride Sukanta Bhattacharyya, Lanchi Vo, Owen W. Gooding, Jeff W. Labadie | ||
| 102 | Steps toward the preparation of thioglycoside dendrimers Michael J. Panigot, Angela R. Buckman, Matt Whiteside, Jeremy Lamb | ||
| 103 | Arylation of 3-haloindoles facilitated by transient protecting group strategies Anthony W. Thompson, Jocelyn Wang, Marzia Villa, Ryan Schoenfeld | ||
| 104 | Novel synthesis of 5-alkyl isoquinolines Sean C. Turner, Chih-Hung Lee, Arthur Gomtsyan, Tammie K. White | ||
| 105 | 3-Indolyl methylphosphonate and methylphosphonothioate as indicators for enzyme-based decontamination of organophosphonoate agents Mark D. Winemiller, Fu-Lian Hsu, Fred Berg, Tu chen Cheng, Vipin K. Rastogi | ||
| 106 | Enantioenriched 2-(metalated)-pyrrolidines G Seelhammer | ||
| 107 | Nucleophilic substitutions of halogenated triazoles via modifications to adjacent nitrogens Sarah L. Poe, David R. Haines | ||
| 108 | Rare-earth metal-catalyzed sulfonylation reactions of N-(phenylsulfonyl)pyrroles Daniel M. Ketcha, David J. Malwitz | ||
| 109 | DMF-DMA assisted novel Friedel-Crafts acylation of thiochroman Yuezhong Wen, Weiping Liu | ||
| 110 | Synthesis of multi-substituted tetrahydroquinoxalines Xu Bai, Lianyou Zheng, Jinchang Wu | ||
| 111 | Microwave-assisted synthesis and elaboration of fluorescein and rhodamine derivatives Juan C. Castro, Guan-Sheng Jiao, Jin Wook Han, Kevin Burgess | ||
| 112 | Isomer-pure synthesis of linear polycyclic aromatic heterocycles Brigitte Wex, Bilal R. Kaafarani, Douglas C. Neckers | ||
| 113 | Paper Withdrawn | ||
| 114 | Synthesis of indole dimer derivatives as potential anti-tubercular drugs Anusha Vable, Wayland E. Noland | ||
| 115 | Design, synthesis, and biological applications of new water-soluble 4,9-diamino-3,10-perylenequinones Xihuai Qiang, Chaobin Zheng | ||
| 116 | Synthesis of 2-[(R-phenyl)amine]-1,4-naphthalenediones and their biological activity Lluvia Itzel López, Elisa Leyva, Juan C. Racero | ||
| 117 | 4,8-Ditoluoyl-1,5-dihydroxynaphthalene: Efficient synthesis of multi-gram quantities Daniel S. Tyson, Michael A. Meador | ||
| 118 | Synthetic [2+2+2] approach to opening [60]fullerene by modification of the cage electronic structure Shih-Ching Chuang, Saeed I. Khan, Yves Rubin | ||
| 119 | New napelline-type diterpene alkaloid from aconitum brunneum hand-mazz Liming Gao, Xiaomei Wei, Li Yang | ||
| 120 | Two new diterpene alkaloids from aconitum spicatum stapf in ann Liming Gao, Xiaomei Wei, Li Yang | ||
| 121 | Novel synthesis of C-13 labeled pyrazinone thrombin inhibitors and elucidation of metabolic activation pathways Jonathan Z. Ho, Matthew P. Braun, Raju Subramanian, Ying-Duo Gao, Dennis C. Dean, David G. Melillo | ||
| 122 | Synthesis of phakellistatin 13 and conversion to phakellistatin 3 and isophakellistatin 3 David L. Van Vranken, Kevin L. Greenman, Dana M. Hach | ||
| 123 | Development of a scalable route to a pyridoquinoxaline antiviral compound William R. Perrault, Paul M. Herrinton, Richard A. Hohler, Joseph W. Strohbach, Steven P. Tanis, Malcolm W. Moon | ||
| 124 | A novel cascade reaction to form indolizidine and quinolizidine alkaloids: Facile syntheses of (±)-epilupinine and (±)-tashiromine Stephen F. Martin, Shawn M. Amorde | ||
| 125 | Studies toward the synthesis of oxazolomycin: Stereoselective cyanosilylation of hindered cyclic ketones Mark G Moloney, Muhammad Yaqoob | ||
| 126 | One-pot synthesis of procaine and other pharmaceuticals Hong Yang, Fernand C. Thyrion | ||
| 127 | Synthesis of benzoxocane-containing natural products: Heliannuol A, K, and helianane James R. Vyvyan, Steven T. Staben, Ryan E. Looper, Celeste Loitz | ||
| 128 | Cyclic fluoroethers via the intramolecular cyclization of alkenyl alcohols Melvin L. Druelinger, Daniel K. Lesniewski, Masato Yamaguchi | ||
| 129 | Synthesis of benzofuroxans by oxidation of 2-nitroanilines and thermal and photochemical cyclization of arylazides Mariana Salgado, Juan C. Racero, Elisa Leyva | ||
| 130 | Synthesis of [2H,5H-dihydrofuran-3-yl]ketones Kelsie J Betsch, Jetty Duffy-Matzner | ||
| 131 | Intramolecular cyclization reactions of cyclic hydroxysulfone derivatives: New annulation reactions leading to oxacyclic ring systems Aravamudan S. Gopalan, Yuan Liu, Hollie K. Jacobs | ||
| 132 | Application of Montmorillonite clay in natural products synthesis Matthew R. Dintzner, Kristen M. McClelland, Kara M. Morse | ||
| 133 | Simple and convenient synthesis of coumarin-3-carboxamides N. Srinivasa Reddy, E. Premkumar Reddy, M.V. Ramana Reddy | ||
| 134 | Tandem intermolecular radical addition-rearrangement for azacycle synthesis David M. Hodgson, Shuji Hachisu | ||
| 135 | Diastereoselectivity in the aza-Cope—Mannich cyclization: Application to the synthesis of pyrrolizidine alkaloids Harriet A. Lindsay, Maria C. Milletti, Powen Hsueh, Eun-Hoo Kim | ||
| 136 | Practical syntheses of diazepinoindolines Gregory S. Welmaker, Joan E. Sabalski | ||
| 137 | Toward the synthesis of the alkaloid histrionicotoxin 285A Helen T. Horsley, Andrew B. Holmes, Catherine J. Smith, Ian Collins | ||
| 138 | Synthesis and biological activity of 1-ethyl-7(4-acetyl-1-piperazynil)-6-fluoroquinolone-3-carboxylic acid Elisa Leyva, Alicia Sagredo, Angeles Cabrero, Denisse A. de Loera, Socorro Leyva | ||
| 139 | Novel one-pot diversity oriented microwave assisted organic synthesis (MAOS) of pyrazolopyridines and tricyclic pyrazoloquinazolinones, utilizing amino-pyrazoles as a branching module Thomas Nixey, Balan Chenera, Thomas E. Vasquez, Vijay K. Gore, Christopher Hulme | ||
| 140 | Efficient synthesis of 3-substituted pyrimidinones Jae Uk Jeong, Xiaohong Chen, Attiq Rahman, Dennis S. Yamashita, Juan I. Luengo | ||
| 141 | Synthesis of 6-thiopurine analogs Brian H. Keogh Jr., Ryan J. Rafferty, Richard M. Hyslop | ||
| 142 | Synthesis and characterization of substituted 1,4,5,12- tetraaza-triphenylenes Chandima Abeywickrama, A.D. Baker | ||
| 143 | Synthesis of novel pyracyloporphyrins Patrick J. Rauen, Timothy D. Lash | ||
| 144 | Examination of reaction conditions for two-step, one-flask syntheses of meso-substituted corroles via dipyrromethane-dicarbinol and pyrrole G. Richard Geier III, Jeffery Forris Beecham Chick, Jennifer B. Callinan, Christopher G. Reid, Waldemar Auguscinski | ||
| 145 | Examination of the reaction course with different aldehydes in one-flask syntheses of meso-substituted porphyrins Jonathan S. Lindsey, G. Richard Geier III | ||
| 146 | Synthesis of oxynaphthiporphyrin Jane M. Rasmussen, Timothy D. Lash | ||
| 147 | Synthesis of dimethoxytetraarylbenziporphyrins Joseph T. Szymanski, Timothy D. Lash | ||
| 453 | Chiral palladium-phosphinooxazolidine catalyst for the enantioselective Diels-Alder reaction Hiroto Nakano, Yuko Okuyama, Kouichi Takahashi, Yuichiro Suzuki, Reiko Fujita, Chizuko Kabuto | ||
Symposium Grid -- Division of Organic Chemistry -- Session Listing
The 227th ACS National Meeting, Anaheim, CA, March 28-April 1, 2004