ORGNSunday, March 28, 2004

8:00 AM-12:00 PM Anaheim Convention Center -- 303A, Oral
New Reactions and Methodology
Presiding:Stephen A. Miller
8:00 AM 11New silicon-mediated ring expansion of n-sized conjugated cycloalkenones into homoallylic n+3 lactones
Mark A. Hatcher, Kristina Borstnik, Gary H. Posner
8:20 AM 12Unexpected cycloaddition chemistry of nitrile oxides from density functional theory
Zhi-Xiang Yu, K. N. Houk
8:40 AM 13Temporary silicon tethered rhodium(I)-catalyzed intramolecular [4+2+2] cycloadditions: Studies toward the total synthesis of (+)-epoxydictymene
P. Andrew Evans, Erich W. Baum
9:00 AM 14Ring-opening metathesis/oxy-Cope rearrangement: A new strategy for the synthesis of bicyclic medium ring-containing compounds
Brian H. White, Marc L. Snapper
9:20 AM 15New domino cyclization and couplings with nickel enolates
Gireesh M Mahandru, Andy R. L. Skauge, Sanjoy Chowdhury, Kande K. D. Amarasinghe, Mary Jane Heeg, John Montgomery
9:40 AM 16Synthesis of linear triquinanes by round-trip radical cyclizations
Jonathan C. Tripp, Dennis P. Curran
10:00 AM 17Air-initiated reactions: Vinyl cyclopropane openings with aryl sulfur radicals
Mitchell A. deLong, Julie A. Mathews, Fred C. Wireko, Amanda L. Ritter, Anna D. Gudmundsdottir
10:20 AM 18Synthesis of spirodienones by electrophilic intramolecular ipso-cyclization of N-(2-alkynyl)-N-(4-methoxyphenyl)amides
Xiaoxia Zhang, Richard C. Larock
10:40 AM 19Ring-opening reactions of 2-isoxazolines and 2-isoxazoles
Martin G. Kociolek, Kyle P. Kalbarczyk, Nicholas G. Straub, Jolene V. Schuster, Elizabeth J. Marton
11:00 AM 20Synthesis and nucleophilic substitution reactions of eight-membered-ring oxocarbenium ion precursors containing a remote alkyl or alkoxy substituent
K.A. Woerpel, Stephen Chamberland
11:20 AM 21Sulfoxide covalent catalysis: Application to glycosidic bond formation
Timothy A. Boebel, David Y. Gin
11:40 AM 22P-Heterocyclic building blocks: Utility in natural product synthesis
Alan Whitehead, Paul R. Hanson

New Reactions and Methodology -- Next Session

Symposium Grid -- Division of Organic Chemistry -- Session Listing

The 227th ACS National Meeting, Anaheim, CA, March 28-April 1, 2004