ORGN 368 |
| Dalit Rechavi, Alessandro Scarso, and Julius Rebek Jr. The Skaggs Institute for Chemical Biology and The Department of Chemistry, The Scripps Research Institute, 10550 N. Torrey Pines Rd., MB-26, La Jolla, CA 92037 |
| The dimeric capsule 12 is a good host for small molecules and molecular pairs. We present here research concerning isotope effects on the non-covalent interactions between deuterated and non-deuterated isomers and the capsule 12. The isomers were put in contact simultaneously with the capsule, and the constants for the equilibrium of the type shown in Figure 1 were calculated using NMR measurements. Surprisingly large isotope effects were observed. |
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Physical Organic, Combinatorial, Materials, Molecular Recognition
8:00 PM-10:00 PM, Tuesday, March 30, 2004 Anaheim Convention Center -- Hall A, Poster
Sci-Mix
Division of Organic Chemistry |
