ORGN 97 |
| Thomas M. Mitzel, Department of Chemistry, Trinity College, 300 Summit Street, Hartford, CT 06106 and Annie Troutman, Chemistry, Trinity College, 300 Summit Street, Hartford, CT 06106. |
Formation and control of carbon-carbon bonds are an essential part of organic synthesis. Indium promotes these types of formations and its utilization has advantages over traditionally used metals. Historically, Indium metal has shown a preference in adding to carbonyl moieties in a 1,2- rather than a 1,4-fashion. In the system shown below, Michael-type of additions have been witnessed. This poster will focus on the mechanistic pathway leading to formation of these "Michael Products" by either 1,4-addition or Cope Rearrangement and use of this technology in formation of ene-diyne molecules.
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New Reactions and Methodology, Metal-Mediated Reactions, Heterocycles and Aromatics
8:00 PM-10:00 PM, Sunday, March 28, 2004 Anaheim Convention Center -- Hall A, Poster
Division of Organic Chemistry |