ORGN 146 |
Synthesis of oxynaphthiporphyrin
| Jane M. Rasmussen, Department of Chemistry, Illinois State University, Normal, IL 61790-4160 and Timothy D. Lash, Department of Chemisty, Illinois State University, Normal, IL 61790-4160. |
Carbaporphyrins, porphyrin analogues where one or more of the usual pyrrole subunits are replaced with carbocyclic rings, have attracted considerable interest due to their unique spectroscopic properties and their ability to form novel organometallic complexes. Oxynaphthiporphyrin (1), a novel porphyrin analogue incorporating a naphthalene ring, has been synthesized by the ‘3 + 1’ methodology. The proton NMR spectrum for (1) shows a stronger diatropic ring current than had been observed for the related carbaporphyrinoid (2). |
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New Reactions and Methodology, Metal-Mediated Reactions, Heterocycles and Aromatics
8:00 PM-10:00 PM, Sunday, March 28, 2004 Anaheim Convention Center -- Hall A, Poster
Sci-Mix
8:00 PM-10:00 PM, Monday, March 29, 2004 Anaheim Convention Center -- Hall A, Sci-Mix
Division of Organic Chemistry
The 227th ACS National Meeting, Anaheim, CA, March 28-April 1, 2004
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