Encapsulated nitrosating reagents (ENR)

ORGN 380

Yanlong Kang1, Grigory V. Zyryanov1, and Dmitry M. Rudkevich2. (1) Department of Chemistry & Biochemistry, University of Texas at Arlington, Box 19065, Arlington, TX 76019, (2) Department of Chemistry and Biochemistry, The University of Texas at Arlington, 502 Yates Street, Arlington, TX 76019-0065
Encapsulated nitrosating reagents (ENR) will be introduced. These are prepared upon chemical fixation of NO2/N2O4 by calixarenes. Size – shape selective nitrosation of amides will be presented. Solid supported ENR and their use in preparative organic chemistry will be discussed.