ORGNThursday, September 11, 2003

8:00 AM-12:00 PM Sheraton New York -- Royal Ballroom A,Oral
Metal-Mediated Reactions and Syntheses
Presiding:Michael G. Organ
8:00 AM 681Palladium coupling of thioimidates with alkylzinc reagents
Peter A. Jacobi, William P. Roberts, Indranath Ghosh
8:20 AM 682Pd and Pt-catalyzed cation-olefin reactions
Michel R. Gagné, William D Kerber
8:40 AM 683New mechanistic insights into metal-catalyzed cross coupling and allylic substitution reactions
Michael G. Organ, Anita Villani, Yvette Majkut, Stephen J. Hynes, Eamon Comer
9:00 AM 684The palladium catalyzed coupling of imines, carbon monoxide and acid chlorides: A simple building block approach to heterocycle synthesis
Bruce A. Arndtsen
9:20 AM 685Palladium(0) catalyzed amination, Stille coupling, and Suzuki coupling of electron-deficient aryl fluorides
Shu Yu, Young Mi Kim
9:40 AM 686Palladium-catalyzed oxidation and kinetic resolution of alcohols using molecular oxygen
David R. Jensen, Michell J. Schultz, Matthew S. Sigman
10:00 AM 687Development of high activity and selectivity Pd/C debenzylation catalysts for organic synthesis
Jian Ping Chen, George Lazar, Alan Wiese, Charles Penquite
10:20 AM 6881,4-Palladium migration from an arene to an imine via C-H activation, followed by arylation: Synthesis of fluoren-9-ones
Dawei Yue, Richard Larock
10:40 AM 689An efficient, regio- and stereoselective palladium-catalyzed route to tetrasubstituted olefins
Chengxiang Zhou, Richard C. Larock
11:00 AM 690Synthesis of dihydrofuroflavonoids via palladium-catalyzed annulation of 1,3-dienes by o-iodoacetoxyflavonoids
Richard C. Larock, Roman V. Rozhkov
11:20 AM 691Palladium-catalyzed electrophilic substitution of allyl acetates in the presence of bis(pinacolato)diboron
Kalman J. Szabo, Sara Sebelius, Olov A. Wallner
11:40 AM 692Palladium-catalyzed electrophilic substitution via mono-allylpalladium intermediates
Kalman Szabo, Niclas Solin, Johan Kjellgren

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The 226th ACS National Meeting, New York, NY, September 7-11, 2003