ORGNMonday, September 8, 2003

8:00 PM-10:00 PM Javits Convention Center -- North Pavillion,Sci-Mix
Sci-Mix
Organizer:L. McElwee-White
 85Activation of kenner's N-Acyl sulfonamide "safety-catch" linker using Pd(0)-catalyzed allylation
Yi He, Laura L. Kiessling
 87Asymmetric synthesis of 3-aminohexose glycals: a 7-step synthesis of a protected vancosamine glycal
Wonsuk Chang, Kathlyn A. Parker
 93Total synthesis of molluscan polypropionates using a novel Lewis acid catalyzed cyclization
Aubry Miller, Dirk Trauner
 101Room temperature ionic liquids from a biorenewable resource - D-Fructose
Maurice Okello, Scott T Handy
 108Oxocarbenium ion cyclizations for the synthesis of fumagillin analogues
Fatoumata Camara, Johana Angarita, Galyna Pushchinska, David R. Mootoo
 109New reagents for asymmetric electrophilic amination
Alan Armstrong, Ian E. Edmonds, Martin Swarbrick
 115Diastereoselective synthesis of 2,6-cis-disubstituted tetrahydopyranones: Studies toward the enantioselective preparation of tetrahydropyranone natural products
Christopher A. Lee, Paul E. Floreancig
 120CsOH-promoted epoxide ring-opening with phosphines: Mild and efficient synthesis of monohydroxyphosphines
Ashlee A. Robinson, Brandon Frank, Daniel L. Fox, Ralph Nicholas Salvatore
 131Radical-induced cyclopentannulation using nitroaldol(Henry)-derived intermediates
Frederick A. Luzzio, Joel P. Ott
 134Microwave assisted multi-component reactions
Heather Tye, Mark Whittaker, Sarah M Ireland
 148Optimization of a process for the preparation of the farnesyl transferase inhibitor BMS-214662
Zhenrong Guo, Boguslaw M. Mudryk, Zhinong Gao, Terence Moore, Cary McConlogue, David Kronenthal, Melanie Miller, Chien-Kuang Chen
 151The development of high-load, soluble reagents via ROMP: Oligomeric sulfoxides and benzyl sulfonates
Mianji Zhang, Joel D. Moore, Daniel L. Flynn, Paul R. Hanson
 156Progress towards a diversity-oriented synthesis of linear polyketides
Daniel E. Macks, James M. Rogér, Derek S. Tan
 164An efficient capping residual hydroxythiophenol on solid support for synthesis of high quality compound library
Luyong Jiang, Alex Chucholowski, Rongshi Li
 168Development of pseudoephedrine chiral linkers for asymmetric alkylations on solid phase
Panee C. Hutchison, Tom D. Heightman, David J. Procter
 174Synthesis of enantiomerically pure tetrahydrofurans using ylides: Application to the total synthesis of haterumalide NA
Jennifer Schomaker, Pulgam Veera Reddy, Babak Borhan
 176Synthetic studies toward dregeanin. Facile construction of the saturated eight-membered lactone ring
Keith R. Buszek
 184Synthesis of M3 and M1 metabolites of HIV protease inhibitor Nelfinavir Mesylate
Aniruddha P. Patwardhan, Mitali Ghoshal, Jason Klein, Christa Hubner-Parajsz, Josef Endl, Sigrun Metz, Angela Puhlmann, Gerald Sigler, Jane Tsai, Joseph Passarelli
 194Exploiting olefin metathesis for the construction of the core of SCH 351448
Michael T. Crimmins, Grace R. Smalley
 198New approaches to the 13C labelling of (+)-catechin
Neil D. Forrest, Richard C. Hartley, Alan Crozier
 206Utilization of hidden meso-symmetry towards the synthesis of the C22-C36 segment of halichondrin B
Valerie A. Keller, Steven D. Burke
 207Total synthesis of a conjugate of a NAALADase inhibitor
Pingyu Ding, Paul Helquist, Marvin J. Miller
 363Synthesis and activity of soluble polymer-supported ruthenium carbene complexes: Robust, recyclable and reusable catalysts for olefin metathesis
Adalie R. Motta, Qingwei Yao
 370Site-specific aminoglycoside derivatives for use in Fluorescence Polarization Immunoassays
Mitali Ghoshal, Gerald Sigler, Jane Tsai, Joyce Chang, Cheryl Brenner, Thomas Steppe, Salvatore J. Salamone, Joseph Passarelli
 372Metalation in hydrocarbon solvents: Insights provided by 13C and 7Li studies
D. W. Slocum, S. Brown, S. Dumbris, E. Mullins, D. Woosley, A. Spencer, S. Eilerman, R.W. Holman
 378Intramolecular [4+2] cycloaddition of conjugated enynes with ynamides: An efficient strategy for the synthesis of substituted indolines and indoles
Joshua R. Dunetz, Rick L. Danheiser
 383Chemistry of non-activated aziridines: Synthesis and reactivity
Iain D. G. Watson, Andrei K. Yudin
 388Novel route to 2-substituted benzo[b]thiophenes using functionalised titanium alkylidene reagents
Christine F. Roberts, Richard C. Hartley
 399Synthesis of functionalized ozonides by post-ozonolysis reactions
Yuanqing Tang, Yuxiang Dong, Jonathan L. Vennerstrom
 400Thermodynamic rearrangement synthesis of "perfect" fullerenes C60X18-24-36-48
Andrei A. Gakh, Andrew Y. Romanovich, Albert A. Tuinman, Ad Bax
 408Enthalpies and activation energies of the s-trans - s-cis conformational equilibrium of methyl-substituted 1,3-butadienes
M Squillacote, Fengting Liang
 415Assessing the feasibility for the delivery of oxygen atoms via an optical fiber
Keith B. Thomas, Alexander Greer
 4181-[2-(2-Hydroxypropyl)phenyl]ethanone: A new photoremovable protecting group for carboxylic acids
Anamitro Banerjee, Larry D. Louisiana II, Atemnkeng Walters, Promise K. Yong
 429Memory effects based on intermolecular photoinduced proton transfer
Robert J. Alvarado, Silvia Giordani, Mabel A. Cejas, Francisco M. Raymo
 433Toward block copolymer actuators: Synthesis and electrochemical properties of conducting polymers integrated into polynorbornene-derived scaffolds
Hyun A Kang, Timothy M. Swager
 435Dielectrophoretic orientation and assembly of nanofilaments
Jeffrey W. Baldwin, Pehr E. Pehrsson
 438Perylene-3,4;9,10-tetracarboxydiimide based structures for molecular electronics application
Ping Yan, Arindam Chowdhury, Michael W. Holman, Koon-Cheung Ching, David M. Adams
 439Electroactive films with nanoscaled dimensions and tunable properties
Eden Joy Pacsial, Robert John Alvarado, Daniel Alexander, Francisco M. Raymo
 442Millisecond kinetics using nanoliters of reagents
Helen Song, Joshua D. Tice, Rustem F. Ismagilov
 452Approaches to catalyzing the cation-olefin multicyclization reaction
Michel R. Gagné, Jeffrey W. Anthis, Jeong Hwan Koh, Cheryl M. Mascarenhas, Jeremy Feducia
 460Direct addition of 3,4-dihydroquinazolines to alkenes via C-H bond activation
Robert G. Bergman, Jonathan A. Ellman, Sean H. Wiedemann
 470General cyclisation of 1,5-dienes using catalytic osmium tetroxide
Timothy J Donohoe, Sam Butterworth
 500A novel dynamic kinetic asymmetric transformation concept employing a ruthenium epimerization catalyst together with an enzyme
Michaela Edin, Johannes Steinreiber, Jan-E. Bäckvall
 509Synthesis of 15N-enriched pseudouridine and derivatives
Jean-Paul Desaulniers, Helen Mei-Ping Chui, Christine S. Chow
 513Using designed peptides to study the nature of carbohydrate-protein interactions
Marcey L. Waters, Sarah E. Kiehna
 514Small molecule-RNA interactions
Zhaohui Yan, Anne M. Baranger
 519Mechanistic studies of enzymatic catalysis of an intermolecular Aldol reaction: Quantum mechanical and molecular mechanical calculations of the DERA-catalyzed Aldol reaction
Xiyun Zhang, K. N. Houk
 521@-Tide peptidomimetics in water: Quantification of amino acid side chain-side chain interactions and amino acid conformational preferences in small, stabilized b-hairpins
Scott T. Phillips, Paul A. Bartlett
 525Crosslinked hemoglobin-dye conjugates for photodynamic therapy
David S. Crumrine, Claudia M. Davila, Kenneth Olsen
 529Design and synthesis of artificial carbohydrates based on rigid polyproline scaffolds
Deyun Wang, Ryan J. Casey, Paramjit S. Arora
 533Synthesis of chemically modified thiopeptide antibiotics
Adrian P. Revington, Philip A.S. Lowden
 539Photolabile lipids based on dithiane-carbonyl adducts: toward light-sensitive liposomes
Andrei G. Kutateladze, Zaiguo Li
 542Synthesis and antiproliferative properties of novel unnatural ceramide analogues
Robert Bittman, Jiong Chun, Hoe-Sup Byun, Gilbert Arthur
 544Crosslinking of synthetic cell surface receptors by protein ligands triggers endocytosis mediated by lipid rafts
Siwarutt Boonyarattanakalin, Scott E Martin, Blake R. Peterson
 549Enzyme catalytic stability in organic solvents
Gabriel Barletta, Amaris Ferrer, Marc D. Legault
 553Modifications around the carboxylate group of the tryptophanyl tRNA synthetase inhibitor Chuangxinmycin: Active non-charged analogues and tight sterical constraints
Dieter W. Hamprecht, Murray J B Brown, Martin J. Hibbs, Richard L. Jarvest, Lucy Mensah, Peter J. O'Hanlon, Andrew J. Pope, Christine M. Richardson
 562Temperature-dependent self-complexing behavior of tethered cyclophanes in solution
Yi Liu, J. Fraser Stoddart
 571Metal-mediated self-assembling porphyrins for stereochemical determination
Courtney C. Olmsted, Qifei Yang, Babak Borhan
 577Mediation of protein activity using nanoparticle-based receptors
Nicholas O. Fischer, Catherine McIntosh Goodman, Ayush Verma, Joseph M. Simard, D. Joseph Jerry, Vincent M Rotello
 587Fluorescent coatings for dopamine detection
Mabel A. Cejas, Francisco M Raymo
 590Understanding origin of enantioselection without steric reasoning: A general electronic theory for asymmetric induction and kinetic resolution
David Zhigang Wang
 598Highly efficient syntheses of polyfunctional lactones and lactams via Rh(I)-catalyzed cycloisomerization
Aiwen Lei, Minsheng He, Jason P. Waldkirch, Xumu Zhang
 607a-Aryl quaternary centers via diastereoselective multi-component coupling reactions
Christopher A. Davies, Nicholas J. Lawrence, Matthew Gray
 610OH - Pd(0) hydrogen bond in palladium-catalyzed allylic alkylation
Anders Frölander, Tebikie Wondimagegn, Kristina Hallman, Mats Svensson, Christina Moberg
 615Asymmetric synthesis of novel trifluoromethyl substituted epinephrine derivatives
Jeffrey R. Ammann, Michael Crowe, Jonathan West
 622Synthesis of chiral ß-amino esters and amides via a highly diastereoselective hydrogenation of chiral enamines
Norihiro Ikemoto, David M. Tellers, Nelo Rivera, Spencer D. Dreher, Jinchu Liu, Eugenia Njolito, Angie Huang, Yi Hsiao, J. Christopher McWilliams, J. Michael Williams, Yongkui Sun, Joseph D. Armstrong, David J. Mathre, Edward J. J. Grabowski
 624Stereoselective synthesis of polyhydroxyl surfactants and investigation of the influence of absolute configuration on surface chemical behavior
Peter Somfai, Kristina Neimert-Andersson

Symposium Grid -- Division of Organic Chemistry -- Session Listing

The 226th ACS National Meeting, New York, NY, September 7-11, 2003