ORGNTuesday, September 9, 2003

8:00 PM-10:00 PM Hilton New York -- Americas Hall 1,Poster
Physical Organic, Materials, Heterocycles, Aromatics, Metal-Mediated Reactions
Organizer:L. McElwee-White
359A novel regioselective Heck-vinylation of enamides. Investigation of fluorous-tagged bidentate ligands for rapid separation
Karl S. A. Vallin, Qisheng Zhang, Mats Larhed, Dennis P. Curran, Anders Hallberg
360Computational studies of vinyl-stabilized halonium ions
Howard Haubenstock, Ronald Sauers
361Regioselectivity of lithiated nitriles addition to enones
Margaret M. Biddle, Hans J. Reich
362Solution structures and chelation strengths of vinyllithium reagents
Kevin L. Jantzi, Hans J. Reich
363Synthesis and activity of soluble polymer-supported ruthenium carbene complexes: Robust, recyclable and reusable catalysts for olefin metathesis
Adalie R. Motta, Qingwei Yao
364A convenient preparation of a novel class of imidazo[1,5-a]pyridines: Decisive role by ammonium acetate in chemoselectivity
Jie Wang, Jason Mason, Donald VanDerveer, Ke Feng, Xiu R. Bu
365Synthesis of novel ether, ketone, sulfone-linked biphenyl monomers by Suzuki cross-coupling reactions
Jiangtao Hao, David A. Boyles, John T. Bendler
366Synthesis of novel phenanthrolines and phthalocyanines
Chandima Abeywickrama, A. D. Baker
367Synthesis of some nine- and ten-membered aromatic lactones via electrophilic heteroatom cyclizations
David P. Brown, Lalitha Krishnamurthy
368Synthesis of asymmetric bisphenol monomers with biphenyl groups by the Suzuki reaction of bis(4-benzyloxyphenyl)borinic acid in aqueous solvents
Jiangtao Hao, David A. Boyles, John T. Bendler
369Structure-property relationship studies in a class of discotic liquid crystals
Piotr Kaszynski, Monika Sienkowska, John M. Farrar, Wiktor Piecek, Paul A. Heiney, Fan Zhang
370Site-specific aminoglycoside derivatives for use in Fluorescence Polarization Immunoassays
Mitali Ghoshal, Gerald Sigler, Jane Tsai, Joyce Chang, Cheryl Brenner, Thomas Steppe, Salvatore J. Salamone, Joseph Passarelli
371Refined synthesis of 1,9-diacyldipyrromethane
Shun-ichi Tamaru, Justin Youngblood, Kannan Muthukumaran, Lianhe Yu, Jonathan S. Lindsey
372Metalation in hydrocarbon solvents: Insights provided by 13C and 7Li studies
D. W. Slocum, S. Brown, S. Dumbris, E. Mullins, D. Woosley, A. Spencer, S. Eilerman, R.W. Holman
373Microwave enhanced synthesis of unusual nitrogen heterocycles: Troger's base and hexaaza-isowurtzitane
Maghar S. Manhas, Ajay K. Bose, Subhendu N. Ganguly, Atri Guha, Reddy Damavarapu
374New approaches to nitrogen-containing bicyclic scaffolds from iminium ion precursors
Yu Chen, Andrei K. Yudin
375Control of sulfur neighbouring group participation exploited in a general synthesis of piperidines
Mairi Gibson, Louis J. Farrugia, Richard C. Hartley
376Intramolecular [4 + 2] cycloaddition of conjugated enynes with arynes: An efficient strategy for the construction of highly condensed polycyclic aromatic and heteroaromatic compounds
Martin E. Hayes, Rick L. Danheiser
377Synthesis of highly-substituted azulenes and polyazulenes. Transition metal-mediated coupling reactions of azulenyl halides, sulfonates, and azulenylmetal compounds
Aimee L. Crombie, Kevin M. Shea, John L. Kane, Rick L. Danheiser
378Intramolecular [4+2] cycloaddition of conjugated enynes with ynamides: An efficient strategy for the synthesis of substituted indolines and indoles
Joshua R. Dunetz, Rick L. Danheiser
379Synthetic methods towards substituted lactam lactols
Jonathan Rosen, Todd D. Nelson, Mark A. Huffman, James M. McNamara, Peter G. Dormer, K. M. J. Brands
380A novel synthetic approach to 6,7-dihydro-5H-imidazo[1,5-a]pyrazin-8-ones
Ariamala Gopalsamy, Mengxiao Shi
381A practical oxone-mediated high-throughput solution-phase synthesis of benzimidazoles from 1,2-phenylenediamines and aldehydes and its application to preparative scale synthesis
Pierre L. Beaulieu, Bruno Haché, Elisabeth von Moos
382Benzo-13-arylphenalene: A progress report
Jelena Zivkovic, Klaus G. Grohmann
383Chemistry of non-activated aziridines: Synthesis and reactivity
Iain D. G. Watson, Andrei K. Yudin
384Concise approach to an unreported class of 5-aryloxy-6-methylaryloxy cytosine analogues
William C. Trenkle, Julia L. Barkin
385An investigation of the Pd 2+ mediated rearrangement of trimethylsilyl substituted cycloproplyimine
Meagan M. Fagan, Banita W. Brown
386Structure determination of N-methyl-1,4,6,7-tetrahydro-5H-indazol-5-ones
Kurt A. Josef, D. Reddy, Ming Tao, Robert L. Hudkins
387Unexpected formation of dinaphtho[2,1-b:1’,2’-d]pyran
Harish K. Cherivirala, G L David Gazula
388Novel route to 2-substituted benzo[b]thiophenes using functionalised titanium alkylidene reagents
Christine F. Roberts, Richard C. Hartley
389Synthesis of 3-oxy-1,7-naphthyridine and its tetrahydro and dihydro derivatives
Yahua Liu, Wenshan Li, Lawrence M Sayre
390Dihydrobenzoxazines and tetrahydroquinoxalines by a tandem reduction-reductive amination reaction
Richard A. Bunce, Lu Y. Hale, Jason R. Lewis
391A new synthesis of tacamonine
Tse-Lok Ho, Wen-Chung Chung
392Stereoselective synthesis of hydroxylated N-heterocycles
Sandeep Handa, Manpreet S. Kachala
393Biomimetic synthesis and biological evaluation of racemic rhazinilam analogues
Guangli Yang, Michael C. Edler, M. Katherine Jung, Ernest Hamel, William G. Bornmann
394Compounds on the pathway to quinolines
Robert V. Honeychuck, Wayne M. Stalick, Ramesh R. Pant
395SIBX: a new stabilized o-iodoxybenzoic acid formulation as a mild and selective oxidizing system
Aurélie Ozanne, Laurent Pouységu, Dominique Depernet, Stéphane Quideau
396Electrochemical synthesis of chiral orthoquinone monoketals
Isabelle Fabre, Denis Deffieux, Stéphane Quideau
397Studies toward the total synthesis of the angucyclinone antibiotic aquayamycin
Nathalie Lebrasseur, Stéphane Quideau
398Effects of substituents at the 4-position of the cyclohexanone dipolarophile on the diastereoselectivity of the Griesbaum coozonolysis reaction
Yuxiang Dong, Yuanqing Tang, Jonathan L. Vennerstrom
399Synthesis of functionalized ozonides by post-ozonolysis reactions
Yuanqing Tang, Yuxiang Dong, Jonathan L. Vennerstrom
400Thermodynamic rearrangement synthesis of "perfect" fullerenes C60X18-24-36-48
Andrei A. Gakh, Andrew Y. Romanovich, Albert A. Tuinman, Ad Bax
401A facile thermal conversion of arylcyanoguanidines to 2,4-diaminoquinazolines
Bin Shao, Jin-cheng Huang
402Novel synthesis of 6-alkoxycarbonyloxy-4-alkyl-2-aryl-4H-thieno[3,2-b]pyrrole-5-carboxylic acid alkyl esters via the rhodium(II)-mediated reactions of 2-diazo-3-[3-alkoxycarbonyl-alkyl (or aryl)-amino]-5-aryl-thiophen-2-yl]-3-oxo-propanoic acid alkyl esters
Dong Joon Lee, Kyongtae Kim
403Generation of highly acidic sp3carbons in pyrroles and indoles
Simona Guidotti, Isabella Camurati, Francesca Focante, Gilberto Moscardi, Luigi Resconi, Rino Leardini, Daniele Nanni
404Synthesis of new ring systems: Isomeric 1,2,4-triazolopyrimido[4",5":4',5']thieno[3',2':5,6]pyrido[3,2-c]cinnolines and other related systems
Mahmoud Badr, A.A. Geies, M.S. Abbady, A.A. Dahy
405Strong conformational preferences in the transition state and tetrahedral intermediates for the acylation reactions: Relevance to inhibitors of lipases and esterases
Yu Takano, K. N. Houk
406Synthesis and photophysical properties of new C60-porphyrin dyads
Michael A. Fazio, David I. Schuster
407Thermodynamics, kinetics and decay paths of phosphadioxirane
Ruomei Gao, David G. Ho, Shabana Afzal, Ha-Yong Chung, Jeff Celaje, Matthias Selke
408Enthalpies and activation energies of the s-trans - s-cis conformational equilibrium of methyl-substituted 1,3-butadienes
M Squillacote, Fengting Liang
409Photochemistry of coumarin-3-peroxy acid tert-butyl ester
Dmitry E Polyansky, Douglas C. Neckers
410Relative rates of the gas phase SN2 and E2 reactions of alkyl bromides and alkyl iodides
Scott Gronert, Adelaide Fagin, Keiko Okamoto, Lawrence M. Pratt, Sudha Mogali
411Solvent effects on the aggregation state of lithium dialkylaminoborohydrides
Lawrence M. Pratt, Sudha Mogali, Kevin Glinton
412Relative reactivity ratios for the chlorination of 3o:2o:1o benzylic hydrogens
Sasan Karimi, Anuska Larkin, David C. Locke, Gopal Subramaniam, Paris Svoronos
413Controlling stereochemistry of addition of 5-substituted 1,3-dithianyl anions to carbonyl compounds
Andrei G. Kutateladze, Zaiguo Li
414Anomalous C-C bond cleavage in heteroatom-centered cation radicals containing vicinal hydroxy group: mechanism revisited and refined
Andrei G. Kutateladze, Zaiguo Li
415Assessing the feasibility for the delivery of oxygen atoms via an optical fiber
Keith B. Thomas, Alexander Greer
416Construction of self-assembled fullerene-porphyrin complexes
Fatma T. Tat, Zhiguo Zhou, Stephen R. Wilson
4171,3,5-Triaxial triaminocyclohexane: The triamine corresponding to Kemp's triacid
Jianwei Bian, Fredric M Menger, Vladimir A. Azov
4181-[2-(2-Hydroxypropyl)phenyl]ethanone: A new photoremovable protecting group for carboxylic acids
Anamitro Banerjee, Larry D. Louisiana II, Atemnkeng Walters, Promise K. Yong
419Study on the photodegradation and quantum yield of near-infrared cyanine dyes solution
Jie Wei, Xiangdi Zheng, Lifeng Liu, jun Zhong
420Ionic liquids a new reaction media in ETC: reactivity and selectivity studies
Mickael Pauvert, William Pomerantz, Olaf Wiest
421Photochemistry and spectroscopy of C2NH isomers
Wendy A. deProphetis, Robert J. McMahon, Christopher S. Simmons, John F. Stanton
422A comprehensive theoretical study on the identity ion pair SN2 reactions of LiX with CH3X (X=F, Cl, Br, I), structure, mechanism and potential energy surface
San-Yan Chu, Yi Ren
423Effect of length and electronic structure in rigid sensitizers for TiO2 semiconductor nanoparticles
Dong Wang, Qian Wei, Elena Galoppini
424Synthesis and properties of the silicon phthalocyanines with two axial fullerene substituents
Dong Jin Kim, Kwang-Yol Kay, Eui Su Kang
425Synthesis of water-soluble fullerene derivatives and their biological applications
Li Fan, Kathryn S. Reinhard, Stephen R. Wilson
426Vapoluminescence switching in a novel conjugated organic compound
Byeong-Kwan An, Soon-Ki Kwon, Soo Young Park
427Syntheses of functionalized fullerene materials leading to molecular recognition
Zhiguo Zhou, David I. Schuster, Stephen R. Wilson
428Synthesis of a novel carbon nanotube/porphyrin system and its photo physical property study
Yi Sun, S. R. Wilson, David I. Schuster
429Memory effects based on intermolecular photoinduced proton transfer
Robert J. Alvarado, Silvia Giordani, Mabel A. Cejas, Francisco M. Raymo
430Novel asymmetric pentacene derivative for organic light-emitting diodes
Bo-Bin Jang, Sang Ho Lee, Zakya H. Kafafi
431A model biosensor using the streptavidin-biotin system and self-amplifying conjugated polymers
Juan Zheng, Timothy M. Swager
432Post-polymerization deprotection to reveal pendent maleimide groups on poly(p-phenyleneethynylene)
Ghislaine C. Bailey, Timothy M. Swager
433Toward block copolymer actuators: Synthesis and electrochemical properties of conducting polymers integrated into polynorbornene-derived scaffolds
Hyun A Kang, Timothy M. Swager
434Conjugated polymer - liquid crystal solutions: dynamic control of intramolecular energy transfer in the end-capped poly-(p-phenylene-ethynylenes)
Evgueni E. Nesterov, Zhengguo Zhu, Timothy M. Swager
435Dielectrophoretic orientation and assembly of nanofilaments
Jeffrey W. Baldwin, Pehr E. Pehrsson
436Digital processing with a three-state molecular switch
Silvia Giordani, Françisco M Raymo, Andrew J P White, David J Williams
437Fluorescent detection of carbon-carbon bond formation
Fujie Tanaka, Rajeswari Thayumanavan, Carlos F. Barbas III
438Perylene-3,4;9,10-tetracarboxydiimide based structures for molecular electronics application
Ping Yan, Arindam Chowdhury, Michael W. Holman, Koon-Cheung Ching, David M. Adams
439Electroactive films with nanoscaled dimensions and tunable properties
Eden Joy Pacsial, Robert John Alvarado, Daniel Alexander, Francisco M. Raymo
440Radical cations of pyrene derivatives in the solid state and the rationalization of crystalline radical cations
Min Yuan, Claire Cohen, Banglin Chen, Daniel Fredrickson, Judith Adams, Stephen Lee, Francis DiSalvo
441Disc-shaped hexaazatriphenylene liquid crystals with six aromatic side chains
Tsutomu Ishi-i, Tomoyuki Hirayama, Thies Thiemann, Kanji Kubo, Akira Mori, Akira Tsuboyama, Taihei Mukaide, Kazunori Ueno, Shuntaro Mataka
442Millisecond kinetics using nanoliters of reagents
Helen Song, Joshua D. Tice, Rustem F. Ismagilov
443Transition-metal catalyzed protocol for rapid assembly of polycyclic compounds
Kay M. Brummond, Lingfeng You
444Synthesis of N-1-aryl-purine nucleosides using copper-catalyzed C-N coupling of boronic acids
J. Jacob R. Strouse, Marjan Jeselnik, Jeffrey B. Arterburn
445Catalytic C-C coupling of N-substituted (pyridin-2-yl)-hydrazine derivatives for the synthesis of bioconjugates
Cesear Corona, Bj K. Bryant, Trevor Luke, Jeffrey B. Arterburn
446Stereospecific cross-coupling of aryl halides with in situ generated chromium E-halovinylidenes
J. R. Falck, D. K. Barma, Anish Bandyopadhyay, Abhijit Kundu, Charles Mioskowski
447Synthesis of benzo-fused nitrogen heterocycles through annulation onto imidazole-, indole-, and pyrrolecarboxaldehydes
James W. Herndon, Jianwei Zhang, Yanshi Zhang, Wayne F.K. Schnatter
448Enantiopure exo- and endo-palladacycles derived from 2,4-disubstituted 2-oxazolines
Kristopher J. Keuseman, Olga N. Gorunova, Christopher J. Dehen, Valery V. Dunina, Irina P. Smoliakova
449New approach to the stereoselective synthesis of polyhydroxy compounds
Hojae Choi, Bruno D. Chapsal, Iwao Ojima
450Rhodium-catalyzed polycyclization reaction of enediynes: Formation of 5-7-5 and 5-7-6 ring systems via the CO-SiCaT and CO-CaT reaction
Victor C. Vassar, Bibia Bennacer, Iwao Ojima
451New strategies to symmetric and unsymmetric cyclic sulfamide analogs of DMP 323: A "sulfur linchpin"/RCM approach
Jung Ho Jun, Joseph M. Dougherty, Maria del Sol Jiménez, Paul R. Hanson
452Approaches to catalyzing the cation-olefin multicyclization reaction
Michel R. Gagné, Jeffrey W. Anthis, Jeong Hwan Koh, Cheryl M. Mascarenhas, Jeremy Feducia
453Comparison of N-heterocyclic carbenes to phosphine ligands in Pd-catalyzed C-C bond formation of nucleosides
John H. Hilmer, Mahesh K. Lakshman
454Development of intramolecular metal-mediated cascade reactions: Hydroboration/Suzuki coupling cascade reactions performed in ionic liquids
William R. Shay, Relindis Y. Mawo, Julius N. Ngwendson
455Development of intramolecular metal-mediated cascade reactions: Hydrostannation/Stille coupling cascade reactions performed in ionic liquids
William R. Shay, Julius N. Ngwendson, Relindis Y. Mawo
456A facile reaction of (Z)-(1-bromo-1-alkenyl)boronate esters with cyclohexylmagnesium chloride. An easy access to alkyl cyclohexyl ketones
Narayan G. Bhat, Mercy Edionwe
457A highly diastereoselective synthesis of (Z)-1-trimethylgermyl-1-alkenes
Narayan G. Bhat, Laura E. Garcia, Victoriano Tamez Jr.
458A novel synthesis of (E)-gem-dimetalloalkenes containing boron and silicon
Narayan G. Bhat, Amanda Tamm Tamm, Amanda Gorena
459[2,3]-Sigmatropic rearrangement of ammonium ylids
Julien P. Sançon, Joseph Sweeney
460Direct addition of 3,4-dihydroquinazolines to alkenes via C-H bond activation
Robert G. Bergman, Jonathan A. Ellman, Sean H. Wiedemann
461Palladium-catalyzed electrophilic substitution of allyl chlorides and acetates via bis-allylpalladium intermediates
Kalman J. Szabo, Olov A. Wallner
462Developing new organochromium-based methodologies: A Pinacol type synthesis of 1,2-diamines and new polymer-supported Cr(II) reagents
Paul J Comina, Severine S Proutiere
463Allyl sulfones as precursors for Pd-catalyzed allylzincation. Natural product synthesis by intramolecular Zn-ene cyclization
Kai Deng, Theodore Cohen
464Chloropurine 2'-deoxynucleoside as a substrate for Pd-catalyzed amination: synthesis of N6-aryl 2'-deoxyadenosine analogues
Paul F. Thomson, Mahesh K. Lakshman
465Palladium-catalyzed amination as a route to N6-aryl adenosine analogues
Mark A. Nuqui, Mahesh K. Lakshman
466Palladium catalyzed coupling of 2'-deoxyguanosine-O6-arylsulfonates with arylamines
Padmaja Gunda, Mahesh K. Lakshman
467Synthesis of the sterically hindered 2'-deoxyadenosine adducts of benzo[c]phenanthrene diol epoxides via Pd catalysis
Shivaputra Patil, Mahesh K. Lakshman
468A direct synthesis of napthalene derivatives
Prabir K Choudhury, Timothy M Rockey, George A Kraus
469Control of stereochemistry and reactivity in palladium-mediated cyclizations
Martin F. Semmelhack, Richard J Hooley
470General cyclisation of 1,5-dienes using catalytic osmium tetroxide
Timothy J Donohoe, Sam Butterworth

Symposium Grid -- Division of Organic Chemistry -- Session Listing

The 226th ACS National Meeting, New York, NY, September 7-11, 2003