ORGNSunday, September 7, 2003

8:00 AM-12:00 PM Sheraton New York -- Imperial Ballroom A,Oral
Asymmetric Reactions and Syntheses
Presiding:Michael S. VanNieuwenhze
8:00 AM 1Studies in asymmetric nucleophilic addition to arene chromium tricarbonyl complexes
Anthony J. Pearson, Harinandini Paramahamsan
8:20 AM 2Asymmetric conjugate additions catalyzed by Cu/bis(sulfonamido)phosphine complexes
Andrew P. Duncan, Isaac J. Krauss, James L. Leighton
8:40 AM 3Practical asymmetric hydrogenation
Xumu Zhang
9:00 AM 4Dynamic kinetic resolution via asymmetric ketone hydrogenation
C. Scott Shultz, Cheng-yi Chen, Shane Krska, Yongkui Sun, Thorsten Rosner, Maureen Howley
9:20 AM 5Asymmetric transfer hydrogenation: A new class of ruthenium(II) arene/ligand dimer
Jérôme C. B. Hannedouche, Martin Wills
9:40 AM 6Mechanistic studies on the highly diastereoselective hydrogenation of chiral enamines to produce beta-amino esters and amides
David M. Tellers, Norihiro Ikemoto, Nelo Rivera, Spencer D. Dreher, Jinchu Liu, Eugenia Njolito, Angie Huang, Yi Hsiao, J. Christopher McWilliams, J. Michael Williams, Yongkui Sun, Joseph D. Armstrong, David J. Mathre, Edward J. J. Grabowski
10:00 AM 7Novel developments in the asymmetric reduction of enones to allylic alcohols: Preparation of allylic alcohol intermediates in the syntheses of avb3–inhibitors
J. Christopher McWilliams, Elizabeth Buck, Kan K. Eng, Roger N. Farr, Edward J. J. Grabowski, Guy R. Humphrey, Joseph Lynch, David J. Pollard, Jess W. Sager, Kathleen Telari, Marjorie M. Waters
10:20 AM 8New approaches to enantioselective synthesis through catalytic asymmetric olefin metathesis
Jesper A. Jernelius, Amir H. Hoveyda, Richard R. Schrock
10:40 AM 9Efficient and practical Ag-catalyzed cycloadditions and Mannich reactions. Enantioselective C-C bond formation in air and water
Nathan S. Josephsohn, Marc L. Snapper, Amir H. Hoveyda
11:00 AM 10Intramolecular cyclization via iron tricarbonyl mediated coupling between cyclohexadienes and pendant olefins (or dienes)
Anthony J. Pearson, Xiaolong Wang
11:20 AM 11First catalytic asymmetric aza-Henry reaction of nitro compounds with imines: A novel approach to optically active a,b-diamino acid derivatives
Kristian Rahbek Knudsen, Nagatoshi Nishiwaki, Tine Risgaard, Kurt V. Gothelf, Karl Anker Jørgensen
11:40 AM 12Understanding origin of enantioselection without steric reasoning: A homohelical electronic theory for asymmetric induction and chiral recognition
David Zhigang Wang

Asymmetric Reactions and Syntheses -- Next Session

Symposium Grid -- Division of Organic Chemistry -- Session Listing

The 226th ACS National Meeting, New York, NY, September 7-11, 2003