We have performed internal ligand-controlled Heck vinylations of enamides with high regioselectivity in moderate to good yields. New bidentate fluorous-tagged 1,3-bis(diphenylphosphino) propane ligands (F-dppp’s) were synthesized and examined. The cationic vinylations of the enamides with F-dppp ligands rendered essentially the same internal selectivity and catalytic activity as in those vinylations where non-fluorous ligands were employed. After reaction, the fluorous-tagged ligand material was easily removed by convenient solid fluorous phase separation. In addition, controlled microwave heating accelerated the palladium-catalyzed reactions and full conversions were achieved after reaction times of only 15-30 min.