ORGN 448 |
Enantiopure exo- and endo-palladacycles derived from 2,4-disubstituted 2-oxazolines
| Kristopher J. Keuseman1, Olga N. Gorunova2, Christopher J. Dehen1, Valery V. Dunina2, and Irina P. Smoliakova1. (1) Department of Chemistry, University of North Dakota, PO Box 9024, Grand Forks, ND 58202-9024, (2) Moscow State University, Russia |
Direct cyclopalladation of a number of enantiopure 2,4-disubstituted 2-oxazolines was carried out using Pd(OAc)2 and NaOAc in AcOH. The synthesized exo- and endo-cyclic dimeric m-acetate cyclopalladated complexes (CPCs) were converted to their corresponding dimeric m-chloro analogs as well as mononuclear PPh3 complexes. Structural characterization of these complexes was done by NMR, IR, UV, and CD spectroscopy, and X-ray analysis. These palladacycles were tested as chiral templates in a number of reactions. |
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Physical Organic, Materials, Heterocycles, Aromatics, Metal-Mediated Reactions
8:00 PM-10:00 PM, Tuesday, September 9, 2003 Hilton New York -- Americas Hall 1, Poster
Division of Organic Chemistry
The 226th ACS National Meeting, New York, NY, September 7-11, 2003
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