ORGN 412 |
| Sasan Karimi1, Anuska Larkin1, David C. Locke2, Gopal Subramaniam2, and Paris Svoronos1. (1) Department of Chemistry, Queensborough Community College-CUNY, 222-05 56 th Ave, Bayside, NY 11364, (2) Department of Chemistry and Biochemistry, Queens College-CUNY, 61-301 Kissena Blvd., Flushing, NY 11367 |
| The free radical chlorination products of several alkyl aromatic compounds containing primary, secondary, and tertiary hydrogens have been investigated and the relative reactivity ratios for the various hydrogens are reported. Sulfuryl chloride was used as the source for the chlorine radicals, and AIBN as the radical initiator. The final objective is to obtain the relative reactivity ratios for 3o:2o:1o benzylic hydrogens and compare them to the corresponding ratios of aliphatic 3o:2o:1o. The relative reactivity ratios for primary, secondary, and tertiary allylic hydrogens is also under investigation. |
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Physical Organic, Materials, Heterocycles, Aromatics, Metal-Mediated Reactions
8:00 PM-10:00 PM, Tuesday, September 9, 2003 Hilton New York -- Americas Hall 1, Poster
Division of Organic Chemistry |