ORGNThursday, March 27, 2003

8:00 AM-11:40 AM Convention Center -- Room 297,Oral
Physical Organic Chemistry: Calculations, Mechanisms, Photochemistry, and High-Energy Species
Presiding:Ron W. Darbeau
8:00 AM 648The N-nitrosoamide-mediated Ritter reaction
Ron W. Darbeau, Rebekah E Gibble, Rebecca S Pease, Edson V Perez
8:20 AM 649Introduction of persistent steric ("persisteric") and pi*-acceptor agostic type interactions
Ron W. Darbeau, Rebecca S Pease, Rebekah E Gibble, Edson V Perez, Luis M Siso, Faith Ayo, Aaron Sweeney
8:40 AM 650Fomenting proton anisochronicity in the CH2D group: Realizing an improved method for assigning the CHDT group via NMR
Benjamin D. Allen, Daniel J. O'Leary
9:00 AM 651Rapid-injection NMR study of iodo- and cyano-Gilman reagents with 2-cyclohexenone: Observation of pp-complexes and their rates of formation
Michael D. Murphy, H. Paul Seagle, Steven H. Bertz, Clifford M. Carlin, Craig A. Ogle
9:20 AM 652Mechanistic studies of the unexpected anti-Markovnikov addition to 1-alkoxy-1,3-cyclohexadienes
Roger A. Rennels, John V. McClusky, Sadie L. Emery
9:40 AM 653Effects of pore confinement on the pyrolysis of 1,3-diphenylpropane in mesoporous silicas
A. C. Buchanan III, Michelle K. Kidder, Phillip F. Britt, Zongtao Zhang, Sheng Dai
10:00 AM 654Reaction of tetracyclopropylethylene with 4-methyl-1,2,4-triazoline-3,5-dione: Novel rearrangement of intermediate product
Duk Kyung Kim, Kevin E O'Shea, Alberto J. Sabucedo
10:20 AM 655Unequivocal determination of the stereochemistry of reactions involving sterically hindered, rotationally restricted 9-fluorenyl anions, radicals, and cations
Cal Y. Meyers, Yuqing Hou
10:40 AM 656Solvolysis-decomposition of 2-adamantylchloroformate: Evidence for two reaction pathways
Dennis N. Kevill, Jin Burm Kyong, Jung-Suk Yoo
11:00 AM 657Acetylacetone in solutions of lithium perchlorate-diethyl ether
Y. Pocker, Greg T. Spyridis
11:20 AM 658Benzocyclobutenone vs cyclobutanone: Acidity differences in strained ring systems
Richard W. Nagorski

Physical Organic Chemistry: Calculations, Mechanisms, Photochemistry, and High-Energy Species -- Next Session

Symposium Grid -- Division of Organic Chemistry -- Session Listing

The 225th ACS National Meeting, New Orleans, LA, March 23-27, 2003