| ORGN | Wednesday, March 26, 2003 | ||
9:00 AM-11:00 AM Convention Center -- Hall I-1,Poster | |||
Heterocycles, Aromatics, Metal-Mediated Reactions, Physical Organic, Materials | |||
| Poster Session | |||
| Organizer: | L. McElwee-White | 482 | Highly diastereoselective multicomponent synthesis of unsymmetrical imidazolines Satyamaheshwar Peddibhotla, Jetze J. Tepe |
483 | Mechanisms of acid-catalyzed Z/E isomerization of imines in acetonitrile James E. Johnson, Houquan Dai, Diana C. Canseco |
484 | New approach to 1’-C-modified riboside scaffold via stereoselective functionalization of D-(+)-ribonic-g-lactone Arnaldo H. Alzerreca |
485 | Spectroscopic identification of carbene and carbenoid intermediates Eric M. Tippmann, Matthew S. Platz |
486 | Synthesis and anion-binding properties of open-chain oligopyrroles Won-Seob Cho, Jonathan L. Sessler, Leah R. Eller, Gheorghe D. Pantos, Blake R. Peterson |
487 | Chiral chemistry through confinement: Photocyclization of tropolone naphthalenone and cyclohexadienone derivatives included in zeolites Lakshmi S. Kaanumalle, Ramamurthy Vaidhyanathan |
488 | Asymmetric photoreaction in isotropic and organized media: Photochemistry of diphenylcyclopropane derivatives Sivaguru Jayaraman, Ramamurthy Vaidhyanathan |
489 | Enhanced enantio- and diastereoselectivity via confinement: Norrish-Yang photocyclization of a-oxoamides and 2-benzoyladamantane derivatives within zeolites Arunkumar Natarajan, Ramamurthy Vaidhyanathan |
490 | New blue and orange fluorescent compounds for an organic electroluminescent device Hisato Takeuchi, Hiromitsu Tanaka, Makoto Mouri, Tomohiko Mori |
491 | Photosensitized cyclization of alkenyl oximes H. J. P. De Lijser, G. L. Loyo, J. R. Sawyer |
492 | Photosensitized reactions of oximes and oxime ethers H. J. P. De Lijser, J. R. Sawyer, C. K Tsai |
493 | Substituent effects on photosensitized reactions of acetophenone oximes H. J. P. De Lijser, Jason S. Kim, Suzanne M. McGrorty, Erin M. Ulloa |
494 | Determination of self-exchange electron transfer rate constants for very fast radical cation-neutral molecule reactions Logan K. Ausman, Jack R. Pladziewicz |
495 | Solvothermal synthesis of polycyclic aromatic chlorocarbons carbon tetrachloride in one step Su-Yuan Xie, Yin Peng, Meng Chen, Rong-Bin Huang, Lan-Sun Zheng |
496 | Synthesis of 3-ethoxyindoles Ronald W. Clawson Jr., Bjorn G.C. Soderberg |
497 | Synthesis of 4,4’-bisphenolformal Jiangtao Hao, David Boyles, John T. Bendler |
498 | Synthesis of novel macrocyclic polyamine complexes for use as anticancer prodrugs Laurie L. Parker, David J. Robins |
499 | Synthesis of the (a,a)-5,10-bis(2-(para-fluorophynylurea)phynyl)porphyrin and anion-binding studies Dennis H. Burns, Kenichi Calderon-Kawasaki |
501 | Synthesis of tripyrrane analogs and related oxybenziporphyrins from resorcinol and 2-methylresorcinol Kae Miyake, Timothy D. Lash |
500 | Paper Withdrawn | 502 | The quest for hydrocarbon analogs of the porphyrins Denise A. Colby, T. D. Lash |
503 | Superacid-catalyzed reactions of cinnamic acids and the role of superelectrophiles Rendy Rendy, Yun Zhang, Aaron McElrea, Alma Gomez, Douglas A. Klumpp |
504 | Synthesis and characterization of main group IV metal complexes bearing indole moieties Taeboem Oh, Valerian Dragutan, Alex Schultz, Tania Tasu, Bernd Wrackmeyer |
505 | Synthesis and structure of preorganized C3-symmetric trilactam scaffolds with convergently oriented thiolmethyl appendages John E. Campbell, Steven D. Burke |
506 | Synthesis of 2,3-diaminodihydropyrroles via a thioimidate-cyclopropane rearrangement Christina Ng, Ronald K. Chang, Mark G. Bock, Scott D. Kuduk |
507 | Preparation and reactions of selenium derivatives of Barton esters: A convenient route to benz[b]seleno[2,3-b]pyridines U. Narasimha Rao, Ramadas Sathunuru, Edward R. Biehl |
508 | Solvent and counterion effects on the NMR of disubstituted triazoliums David R. Haines, Christine I. Worrall, Nalyn Siripong, Amanda C. Doran, Megan Chen Feetham |
509 | Sonogashira coupling routes to fused-ring sydnones Andrew J. Weisner, Kenneth Turnbull |
510 | Metallation in hydrocarbon solvents: The effect of electron density localization of the directing group R. W. Holman, Michael Timmons, Roslyn LeMastus, Phillip Shelton, Gina Jackson, B.D. Woosley, S. Brown, S. Dumbris, A. Spencer, D.W Slocum |
511 | Mixed fused-ring oligomers as precursors to new conjugated systems Karla R. Radke, Katsu Ogawa, Seth C. Rasmussen |
512 | Oxidation products of a thiophene derivative and the synthesis of a novel polycyclic anhydride Joseph W. Vincent, Robert G. Clevenger, Robert D. Ingalls, James A. Watson Jr., Douglas M. Ho, Kathleen V. Kilway |
513 | Design and synthesis of polyhydroxy cavitands Eric Efrain Dueno, Sandeep A. Chapalamadugu, Kirpal S. Bisht |
514 | Dicationic electrophiles: Superacid-catalyzed chemistry of alkynes Rendy Rendy, Yun Zhang, Aaron McElrea, Alma Gomez, Han Dang, Douglas A. Klumpp |
515 | Direct palladium-catalyzed route for isoxazole synthesis Matthew B. Kraft, Cindy C. Browder |
516 | Efforts toward the total synthesis of (-)-galanthamine Keith R. Buszek |
517 | Facile and convenient synthesis of N-acylpyrroles from primary aromatic amides Anil R. Ekkati, Dallas K. Bates |
518 | A novel synthesis of 2-amino-4-(1,3-benzothiazol-2-yl)-5-(2-chloro-5-nitrophenyl)thiazole Osvaldo Cox, Wigberto J. Hernandez, Manuel A. Ramos |
519 | A practical preparation of 5-(ketoaryl)thiazoles Lisa F. Frey, Karen M Marcantonio, Debra Wallace, Cheng-yi Chen, Jerry Murry, Rich D. Tillyer, Ulf H. Dolling, Edward J. J. Grabowski |
520 | Application of the Dakin-West reaction for the synthesis of oxazole-containing dual PPAR-alpha/gamma agonists Alexander G. Godfrey, Dawn A Brooks, James R. McCarthy, David Mitchell, Mary K. Peters, Lynne A Hay |
521 | S-(2–Pyridinyl)-1,1,3,3-tetramethylthiouronium hexafluorophosphate: A new reagent for the synthesis of pyridine-2-thiol esters Philip Garner, Noemi Scardovi, John D Protasiewicz |
522 | A new Biginelli reaction procedure using potassium hydrogen sulfate as the promoter for an efficient synthesis of 3,4-dihydropyrimidin-2(1H)-one Shujiang Tu, Fang Fang, Chunbao Miao, Hong Jiang, Daqing Shi, Xiangshan Wang |
523 | A simple and efficient route to N-functionalized dithieno[3,2-b:2',3'-d]pyrroles: Fused-ring building blocks for new conjugated polymeric systems Katsu Ogawa, Seth C. Rasmussen |
524 | Lequesnamine: A new oxoaporphine alkaloid from Ocotea leucoxylon Michael J. Imler, Mary D. Menachery, R. Rajaraman, Michael P. Cava, Alan J. Freyer, Stone. D. Shi |
525 | Amination of 2,6-diaminopyridines with sterically demanding amines by a thermal protocol Siegfried R. Waldvogel, Andreas Faust, Werner Barkmann |
526 | Structure and properties of some cresolphthalein derivatives Christopher J. Abelt, William E. Brenzovich Jr. |
527 | Aromaticity and antiaromaticity in all-pnictogen cluster compounds: An important consequence for organic chemistry Aleksey E. Kuznetsov, Alexander I. Boldyrev, Hua-Jin Zhai, Lai-Sheng Wang |
528 | Synthesis of fluorescent rhodamine conjugates by reaction of primary amines with rhodamine 2'-esters Jonathan Grote, Maciej Adamczyk |
529 | Toward the total synthesis of selaginoidine Michael P Cassidy, Albert Padwa |
530 | Novel polyphenylene structures related to "cubic graphite" Xianfeng Shen, Douglas M. Ho, Robert A. Pascal Jr. |
531 | Synthesis of 5-amino-6-methoxy-1-(3’,4’,5’-trimethoxyphenyl)-3,4-dihydronaphthalene: A potential anticancer and vascular targeting agent Christopher J. Jelinek, Vani Mocharla, Rogelio Siles, Zhi Chen, Kevin G. Pinney |
532 | General synthetic approach to 2,5-disubstituted pyridines Gregory Lannoye, Darlene Cothron |
533 | Nitrosation reaction of phenols at basic condition with b-cyclodextrin as catalyst Jigang Pan, Yuejun Huang |
534 | Microwave-assisted disubstituted pyrrole synthesis Shahnaz Ghassemi, Peter Rahn, Michael Webb |
535 | Efficient syntheses of biologically active bicyclic oxazolino- and thiazolino[3,2-c]pyrimidin-5,7-diones Joseph Pontillo, C. Chen |
536 | Inhibitor-releasing quinones for reversal photography Thomas R. Welter |
537 | Enantiospecific synthesis of (1R,2S,4R)-4-amino-2-hydroxycyclopentanemethanol (2a) and (1S,3R)-1-aminoocyclopentanemethanol (2b) Jonathan Z. Ho, Rafat M. Mohareb, Jin Hee Ahn, Tae Bo Sim, Henry Rapoport |
538 | New conjugated hole transport materials for solar cells Andrew B Holmes, Taiho Park, Niels Schulte, Saif A Haque, James Durrant, Lucy Otley, Robert J Potter, Chan Im, Heinz Baessler |
539 | Synthesis, optical, and redox properties of alkylated 6,13-diethynylpentacenes John E. Anthony, Christopher R. Swartz |
540 | Donor-sigma-acceptor molecules incorporating a swallowtail perylene-bisimide acceptor Lyle Wescott, Daniell L. Mattern |
541 | Dynamic NMR study of organosulfur compounds: Redox-mediated molecular brake Parag V. Jog, Richard E. Brown, Dallas K. Bates |
542 | Energy transfer across catenane amino acids Yoonkyung Kim, Liam C. Palmer, Csaba Nemes, Julius Rebek Jr. |
543 | AlQ3 derivatives with tunable optical properties Radek Pohl, Pavel Anzenbacher Jr. |
544 | Aryl linker strategies for the synthesis of crown-ether-containing fluoropolymers S. Clark Ligon Jr., D. W. Smith Jr., Chris M. Topping, S. Suresh, Jennifer A. Irvin, Stephen Fallis, D. D. DesMarteau |
545 | Design and synthesis of new organometallic complexes with potential biological activity Valerian Dragutan, Taeboem Oh, Alex Schultz, Tania Tasu, Ileana Dragutan, Mariana Danila, Petru Filip, Bernd Wrackmeyer, Larry R. Sherman |
546 | 1,2-Bis(tetrafluoropyridinylethynyl)benzenes: Synthesis and DNA photocleavage Serguei V. Kovalenko, Igor V. Alabugin |
547 | Novel calamitic liquid crystals: Synthesis and characterization Kevin D. Belfield, Maher A. Qaddoura |
548 | Photophysical and photochemical properties of a new class of photosensitizers for photodynamic therapy Kevin D. Belfield, Claudia C. Corredor |
549 | Chiral phase behavior in photochromic liquid crystals Michel L. Frigoli, Georg H. Mehl |
550 | Investigation of the photochromic properties and of the liquid-crystalline phase behavior of functionalized diarylethene derivatives Michel L. Frigoli, Georg H. Mehl |
551 | Optical switching and the modulation of liquid-crystal properties of functionalized diarylethene derivatives Michel L. Frigoli, Georg H. Mehl |
552 | Synthesis and photophysics of a T-shaped porphyrin-fullerene dyad Ke Li, David I. Schuster |
553 | Synthesis of a universal photolabile cross-linker and its application in AFM imaging Rong Wang, Funing Yan, Liaohai Chen, Chada V. Gopal Reddy |
554 | Photoregulation of hole transfer in DNA studied by a pulse radiolysis-laser flash photolysis combined method Tadao Takada, Kiyohiko Kawai, Sachiko Tojo, Tetsuro Majima |
555 | Photophysical characterization of thieno[3,4-b]pyrazines Daniel J. Sattler, Kari A. Mitchell, Seth C. Rasmussen |
556 | Substituted tris(bipyridyl)ruthenium complexes as selective photosensitizers for electron transfer in organic chemistry Felix S. Lee, Sara Van Rooy, Norman P. Schepp |
557 | Synthesis and characterization of a model electron donor/acceptor system based on a peptide nucleic acid duplex Isil Dilek, Bruce A. Armitage |
558 | Synthesis of photocleavable protecting groups for primary alcohols with applications in the construction of DNA microarrays Garrett M. Zopp, Mary K. Boyd |
559 | Electrocyclization reaction of N-alkylpyridones inside chirally modified zeolites S Karthikeyan, V Ramamurthy |
560 | Bergman cyclization: Ortho effect in benzannelated enediynes Tarek A. Zeidan, Igor V. Alabugin |
561 | Molecular orientation effects on hydrogen transfer rates under diffusional constraints Michelle K. Kidder, A. C. Buchanan III, Phillip Britt |
562 | NMR studies of the cleavage of highly substituted epoxides with organoalane reagents José A. Prieto, Gerardo Torres |
563 | Equilibrium lithium and cesium ion-pair acidities of some b-diketones: Aggregation of lithium and cesium ion pairs of their enolate mono- and dianions Antonio Facchetti, Andrew Streitwieser |
564 | Influence of methyl substituents on the stability and reactivity of 1-aza-2-adamantanone, Kirby's most twisted amide Kathleen M. Morgan, M. Logan Rawlins, Margo Montgomery |
565 | Conformational studies of cyanoformate (HCO2CN) and related compounds Dalephine Davis, Diwakar Pawar, Eric Noe |
566 | Dimethylstannylene: Generation and trapping reactions Dong Zhou, Peter P. Gaspar |
567 | Photochemical behavior of a-azoxy ketones Paul S. Engel, Konstantin P. Tsvaygboym, William B. Smith |
568 | Mechanism of dichlorocarbene addition to benzocyclopropene Ekaterina Zelenova, Dina C. Merrer |
569 | Dichlorocarbene addition to cyclopropenes: A computational study Dina C. Merrer |
570 | Mechanistic investigations of the aqueous breakdown of substituted N-(hydroxymethyl)benzamide compounds as a function of pH Richard W. Nagorski, William J. Tenn III |
571 | Novel regiochemistry in the aqueous singlet oxygen ene reaction of carboxylic acid salts: A comparison of substrate structure Kristina Lynn Stensaas, Anisha Bajaj, Akram Al-Turk |
572 | The location effect of substituents on the Bronsted apha for hydride transfer reactions In-Sook Han Lee, Kyoung Hwha Suh |
573 | Density functional theory investigation of deprotonation of 2,3-dihydrofuran Zhiqing Yan, John F. Sebastian |
574 | Cobalt-catalyzed reductive dimerization of conjugated alkenes: Application to the synthesis of macrocyclic di- and tetralactones Chun-Chih Wang, Chien-Hong Cheng |
575 | Novel Rh-catalyzed cyclization via rhodacycle intermediates: Hydroacylation of dienals and cycloisomerization of trienes Yoshihiro Sato, Yoshihiro Oonishi, Miwako Mori |
576 | Umpolung palladium- and indium-mediated allylations John W. Giraldes, Gregory R. Cook |
577 | New developments in palladium- and indium-mediated allylation Gregory R. Cook, Robert Kargbo, Jason Hallman |
578 | The contribution of prior-coordination to ortho-lithiation: Regiospecific metallation of ortho-methylanisole and dimethylbenzylamine D.W. Slocum, Michael Timmons, Sophia Wang, Adam Watson, Carl Friesen, Dustin Smith, Roslyn LeMastus, Phillip Shelton, Gina Jackson, R. W. Holman |
579 | Trisubstituted olefin synthesis by reaction of benzylic zinc reagents with b,b-disubstituted alkenyl(phenyl)idonium triflates Nichole D. Litvinas, Robert J. Hinkle |
580 | Vinyl aryl ethers from copper-catalyzed coupling of vinyl halides and phenols Zhonghui Wan, Thomas M. Koenig, Y. John Pu, David Mitchell |
581 | Palladium-catalyzed synthesis of isatins and 2-haloisatogens Chet R. Howerton, Björn C. G. Söderberg, Shubhada W. Dantale |
582 | Synthesis of 2-alkylbenzimidazoles Jeff M. Wallace, Björn C. Söderberg |
583 | Synthesis of indanes through coupling of ethynylstyrene derivatives with carbene complexes Lei Zhang, James W. Herndon |
584 | Synthesis, characterization, and elaboration of endo[n.n.n.n] (n = 3 or 4) metacyclophanes Dennis H. Burns, Charles L. Jayne, Sumith A. Kularatne |
585 | Rhodium-catalyzed cross-coupling of allylic alcohols with aryl- and vinylboronic acids in ionic liquids George W Kabalka, Gang Dong, Bollu Venkataiah |
586 | Rhodium(I)-catalyzed tandem hydrosilylation aldol reaction: Synthesis of carbocyclic natural products Marta Freiría, William B. Motherwell, Andrew J. Whitehead |
587 | Metalloporphyrin-based catalytic systems for olefination of aldehydes and ketones with diazo compounds X. Peter Zhang, Ying Chen, Lingyu Huang |
588 | Novel Rh-catalyzed [2+2+2+1] cycloaddition reaction of enediynes Masaki Fujiwara, Victor C. Vassar, Iwao Ojima |
589 | Palladium-catalyzed Heck-type reactions using haloalkenes in place of alkenes in reactions with organic iodides Harold A. Dieck, Thao M. Perry, Ping Xia, Brian P. Harting |
590 | Palladium-catalyzed cleavage of aryl propargyl ether Manojit Pal, Karuppasamy Parasuraman, Koteswar R. Yeleswarapu |
591 | Ligand-controlled asymmetric induction at a transition-metal-bonded stereogenic carbon: Diastereoselective synthesis of oxapalladacycles and development of their synthetic applications Helena C. Malinakova, Janelle L. Portscheller, Sara E. Lilley |
592 | Highly efficient Suzuki coupling reactions of aryl bromides and arylboronic acids catalyzed by Pd(OAc)2/amines under mild conditions Bin Tao, David W. Boykin |
593 | Indium-promoted couplings leading to enediyne formation and oxy-cope rearrangements Thomas M. Mitzel, Annie Troutman |
594 | Preparation of biotin derivatives by catalytic oxidative carbonylation of diamines Yue Zhang, Kara Forinash, Lisa McElwee-White |
595 | Synthesis of lactones and related bicyclic heterocycles by palladium(II)-catalyzed 1,4-oxidation of conjugated dienes Renzo C. Verboom, Anders Persson, Jan-E. Bäckvall |
596 | Toward highly air-stable palladium catalysts for the cross-coupling reactions with unactivated aryl chlorides George Y. Li |
597 | Isoquinolone synthesis via rhodium(II)-catalyzed intramolecular aromatic C-H insertion of a-phenylsulfonyl-a-diazoacetamides Kyung Woon Jung, Advait S. Nagle, Cheol Hwan Yoon, Chiliu Chen |
598 | Efficient synthesis of triols via Rh-catalyzed regioselective intramolecular silylformylation of alkynes Bruno D. Chapsal, Chunhui Jiang, Seung-Yub Lee, Iwao Ojima |
599 | Effect of solvent on the lithium-iodine exchange of primary alkyl iodides: Reaction of t-butyllithium with 1-iodooctane in heptane-ether mixtures William F. Bailey, Jason D. Brubaker, Kevin P. Jordan |
600 | A new titanium tetrachloride mediated synthesis of polysubstituted naphthalenes George W Kabalka, Zhongzhi Wu, Yuhong Ju |
601 | Asymmetric hydrogenation of arylalkenes using iridium imidazol-2-ylidene-oxazoline complex Kevin Burgess, Xiuhua Cui, Marc C. Perry |
602 | A facile reaction of (Z)-(1-bromo-1-alkenyl)boronate esters with cyclopropylmagnesium bromide: An easy access to alkyl cyclopropyl ketones Narayan G. Bhat, Laura E. Garcia, Victoriano Tamez Jr. |
603 | A novel synthesis of capillin and capillen via organoboranes Narayan G. Bhat, Etem T. Chu |
604 | An efficient and environmentally friendly synthesis of C-aryl glucals via palladium(0)-catalyzed cross-coupling reactions of triorganoindium(III) reagents and aryl halides Thomas G Minehan, Smita Awasthi |
605 | Palladium-catalyzed Suzuki cross-couplings of aryl chlorides in the presence of a triarylphosphine Gregory C. Fu, Shih-Yuan Liu |
606 | A general method for the formation of diaryl selenides using copper(I) catalysts Rattan Gujadhur, D. Venkataraman |
607 | Highly efficient epoxidation of cyclic alkene catalyzed by ruthenium complexes Jian Ying Qi, C. W. Yip, Zhong Yuan Zhou, Albert S.C. Chan |
608 | Synthesis and characterization of cobalt complexes containing 2-pyridinecarboxamide ligands and their application in catalytic oxidation of ethylbenzene with dioxygen Jian Ying Qi, Xianjun Li, Zhong Yuan Zhou, Michael C. K. Choi, Albert S. C. Chan, Qi Yun Yang |
609 | Synthesis of benzylic boronates via palladium-catalyzed cross-coupling reaction of bis(pinacolato)diboron with benzylic halides Andre Giroux |
610 | Pd-catalyzed cycloisomerization of 1,6-dienes Guy C. Lloyd-Jones, Paul A. Slatford, I. J. S. Fairlamb, J. P. H. Charmant |
611 | Synthesis of 7-substituted indoles via directed ortho metallation and Suzuki-Miyaura cross-coupling Christian Hartung, Anja Fecher, Bert Nolte, Victor Snieckus |
Symposium Grid -- Division of Organic Chemistry -- Session Listing
The 225th ACS National Meeting, New Orleans, LA, March 23-27, 2003